A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property | |
Lin, Feng1,2; Dong, Yaping1; Peng, Jiaoyu1; Wang, Liping1,2; Li, Wu1; Yang, Bo1 | |
刊名 | PHASE TRANSITIONS |
2016-10-01 | |
卷号 | 89期号:10页码:996-1005 |
关键词 | Slow Evaporation Method Nonlinear Optical Hydrate Borate |
文献子类 | Article |
英文摘要 | A new acentric mixed metal borate of composition K2Ba[B4O5(OH)(4)](2)10H(2)O, has been successfully obtained by slow evaporation solution method. The compound crystallizes in the Orthorhombic space group Pna21 (No.33) with a = 16.8668(7) angstrom, b = 13.0903(5) angstrom, c = 11.5529(5) angstrom and Z = 4. [B4O5(OH)(4)](2-) clusters serve as fundamental building unit linking with BaO8, K1O(6), K2O(7) by common O atoms to form three-dimensional layer structure. The second harmonic generation measurements in the powder samples reveal that the compound exhibits approximately 0.5times that of KH2PO4 (KDP) and phase matching. |
WOS关键词 | CRYSTAL-STRUCTURE ; BARIUM BORATE |
WOS研究方向 | Crystallography ; Physics |
语种 | 英语 |
WOS记录号 | WOS:000387145700003 |
内容类型 | 期刊论文 |
源URL | [http://ir.isl.ac.cn/handle/363002/6366] |
专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 中国科学院青海盐湖研究所 |
作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Salt Lake Comprehens Utilizat Resources Engn Tech, Xining, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Lin, Feng,Dong, Yaping,Peng, Jiaoyu,et al. A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property[J]. PHASE TRANSITIONS,2016,89(10):996-1005. |
APA | Lin, Feng,Dong, Yaping,Peng, Jiaoyu,Wang, Liping,Li, Wu,&Yang, Bo.(2016).A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property.PHASE TRANSITIONS,89(10),996-1005. |
MLA | Lin, Feng,et al."A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property".PHASE TRANSITIONS 89.10(2016):996-1005. |
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