Experimental study on the selective catalytic reduction of NO with C3H6 over Co/Fe/Al2O3/cordierite catalysts

	Experimental study on the selective catalytic reduction of NO with C3H6 over Co/Fe/Al2O3/cordierite catalysts
	Liu, Xin 1; Su, Ya-Xin 1; Dong, Shi-Lin 1; Zhou, Hao 2; Deng, Wen-Yi 1; Zhao, Bing-Tao 3
刊名	Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology
	2018
卷号	46 期号:6 页码:743-753
ISSN号	02532409
英文摘要	The Co/Fe/Al2O3/cordierite catalysts with different Co loadings were prepared by sol-gel and impregnation methods, and their performance in the selective catalytic reduction of NO with C3H6 over catalytic were experimentally studied in a ceramic tubular reactor. The results indicated that 1.5Co/Fe/Al2O3/cordierite showed the highest C3H6-SCR activity with 97% NO reduction in the simulated flue gas at 550 . Cobalt was able to effectively improve the ability of Fe/Al2O3/cordierite catalysts to resist SO2 and H2O in flue gas. When 0.02% SO2 and 3% water vapor were added to the simulated flue gas, the NO reduction efficiency of 1.5Co/Fe/Al2O3/cordierite was almost unaffected, the NO reduction by 1.5Co/Fe/Al2O3/cordierite with C3H6 all surpassed 90%. In contrast, the catalytic activity of Fe/Al2O3/cordierite without cobalt modification was seriously suppressed by SO2 and H2O, the highest NO reduction efficiency of Fe/Al2O3/cordierite was less than 50% within the entire reaction temperature range (200-700 ).XRD and SEM results showed that the surface of 1.5Co/Fe/Al2O3/cordierite after the modification by cobalt became loose, and formed by the cobalt iron and cobalt aluminum metal oxide-based spherical grains.H2-TPR results showed that 1.5Co/Fe/Al2O3/cordierite had better low temperature reduction performance than Fe/Al2O3/cordierite. Py-FTIR results confirmed that Co can dramatically increased the Lewis acid and produced Br∅nsted acid on the catalyst surface. N2 adsorption/desorption characterization results proved that Co can increase the specific surface area of the catalyst. © 2018, Science Press. All right reserved.
出版者	Science Press
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/25218]
专题	中国科学院上海硅酸盐研究所
作者单位	1.School of Environmental Science and Engineering, Donghua University, Shanghai; 201620, China; 2.Changzhou Vocational Institute of Engineering, Changzhou; 213164, China; 3.School of Energy and Power Engineering, University of Shanghai Science and Technology, Shanghai; 200093, China
推荐引用方式 GB/T 7714	Liu, Xin,Su, Ya-Xin,Dong, Shi-Lin,et al. Experimental study on the selective catalytic reduction of NO with C3H6 over Co/Fe/Al2O3/cordierite catalysts[J]. Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology,2018,46(6):743-753.
APA	Liu, Xin,Su, Ya-Xin,Dong, Shi-Lin,Zhou, Hao,Deng, Wen-Yi,&Zhao, Bing-Tao.(2018).Experimental study on the selective catalytic reduction of NO with C3H6 over Co/Fe/Al2O3/cordierite catalysts.Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology,46(6),743-753.
MLA	Liu, Xin,et al."Experimental study on the selective catalytic reduction of NO with C3H6 over Co/Fe/Al2O3/cordierite catalysts".Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology 46.6(2018):743-753.