Volatility diagram of ZrB2-SiC-ZrC system and experimental validation

doi:10.1111/jace.15497

	Volatility diagram of ZrB2-SiC-ZrC system and experimental validation
	Lu, Ying 1; Zou, Ji 2; Xu, Fangfang ; Zhang, Guo-Jun
刊名	JOURNAL OF THE AMERICAN CERAMIC SOCIETY
	2018
卷号	101 期号:8 页码:3627
关键词	microstructure oxidation volatility diagrams ZrB2-SiC-ZrC
ISSN号	0002-7820
DOI	10.1111/jace.15497
英文摘要	A volatility diagram of zirconium carbide (ZrC) at 1600, 1930, and 2200 degrees C was calculated in this work. Combining it with the existing volatility diagrams of ZrB2 and SiC, the volatility diagram of a ternary ZrB2-SiC-ZrC (ZSZ) system was constructed in order to interpret the oxidation behavior of ZSZ ceramics. Applying this diagram, the formation of ZrC-corroded and SiC-depleted layers and the oxidation sequence of each component in ZSZ during oxidation and ablation could be well understood. Most of the predictions from the diagrams are consistent with the experimental observations on the oxidation scale of dense ZrB2-SiC-ZrC ceramics/coatings after oxidation at 1600 degrees C or ablation at 1930 and 2200 degrees C. The reasons for the discrepancy are also briefly discussed.
学科主题	Materials Science, Ceramics
出版者	WILEY
WOS记录号	WOS:000434278100040
资助机构	National Natural Science Foundation of China, Grant/Award Number: 51272266, 51611140121 ; Science and Technology Commission of Shanghai Municipality, Grant/Award Number: 15ZR1445200 ; Shanghai technical platform for testing and characterization on inorganic materials, Grant/Award Number: 14DZ2292900 ; National Natural Science Foundation of China, Grant/Award Number: 51272266, 51611140121 ; Science and Technology Commission of Shanghai Municipality, Grant/Award Number: 15ZR1445200 ; Shanghai technical platform for testing and characterization on inorganic materials, Grant/Award Number: 14DZ2292900
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/24786]
专题	中国科学院上海硅酸盐研究所
作者单位	1.Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Univ Birmingham, Sch Met & Mat, Birmingham, W Midlands, England 4.Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Inst Funct Mat, Shanghai, Peoples R China
推荐引用方式 GB/T 7714	Lu, Ying,Zou, Ji,Xu, Fangfang,et al. Volatility diagram of ZrB2-SiC-ZrC system and experimental validation[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2018,101(8):3627, 3635.
APA	Lu, Ying,Zou, Ji,Xu, Fangfang,&Zhang, Guo-Jun.(2018).Volatility diagram of ZrB2-SiC-ZrC system and experimental validation.JOURNAL OF THE AMERICAN CERAMIC SOCIETY,101(8),3627.
MLA	Lu, Ying,et al."Volatility diagram of ZrB2-SiC-ZrC system and experimental validation".JOURNAL OF THE AMERICAN CERAMIC SOCIETY 101.8(2018):3627.