Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity

doi:10.1016/j.chempr.2018.08.015

	Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity
	Huang, Yun-Hui 5; Liu, Jianjun 4; Kang, Litao 3; Zeng, Rui 5; Huang, Ying 5; Liu, Qing 5; Li, Yuyu 5; Zhang, Yan 1; Yang, Jun 1; Lei, Danni 2
刊名	CHEM
	2018-10-11
卷号	4 期号:10 页码:2463-2478
ISSN号	2451-9294
DOI	10.1016/j.chempr.2018.08.015
英文摘要	Similar to graphite and graphene, aromatic rings are ultra-stable configurations with highly delocalized sp(2)-hybridized electrons, which are the basic units for most organic electrode materials. However, the aromatic rings in organic electrode materials are inaccessible for Nation storage. Here, we have designed a wavy-layered 3D structure of metal-organic compound zinc perylenetetracar boxylates (Zn-PTCA) with stretched space between adjacent perylene planes, which enables aromatic rings activated as Nation storage sites. Such Zn-PTCA delivers a high specific capacity of 357 mAh g(-1) at a current density of 50 mA g(-1) within the potential range of 0.01-2 V versus Na+/Na, corresponding to an eight-electron-transfer process. Experiments and calculations revealed that both C=O groups and aromatic rings are involved in the Na insertion processes. We believe that the present strategy can open up an avenue for developing a big family of 3D open-framework-structured organic materials for application in high-capacity Nation batteries.
资助项目	National Natural Science Foundation of China[51702111] ; National Natural Science Foundation of China[51632001] ; National Natural Science Foundation of China[21573272] ; Program for Changjiang Scholars and Innovative Research Team in University[IRT14R18] ; project of the Innovative Group of Guangdong Province[2014ZT05N013] ; China Postdoctoral Science Foundation[2016M592328] ; Science and Technology Commission of Shanghai Municipality[16DZ2260600] ; Science and Technology Commission of Shanghai Municipality[18511109402]
WOS关键词	GENERALIZED GRADIENT APPROXIMATION ; DENSITY-FUNCTIONAL THEORY ; TOTAL-ENERGY CALCULATIONS ; WAVE BASIS-SET ; COORDINATION POLYMERS ; THERMAL-PROPERTIES ; BATTERIES ; PERFORMANCE ; ELECTRODE ; ANODES
WOS研究方向	Chemistry
语种	英语
出版者	CELL PRESS
WOS记录号	WOS:000447051500025
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; project of the Innovative Group of Guangdong Province ; project of the Innovative Group of Guangdong Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Science and Technology Commission of Shanghai Municipality ; Science and Technology Commission of Shanghai Municipality
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/13231]
专题	中国科学院武汉物理与数学研究所
通讯作者	Huang, Yun-Hui; Liu, Jianjun; Fang, Chun
作者单位	1.Chinese Acad Sci, Natl Ctr Magnet Resonance Wuhan, Key Lab Magnet Resonance Biol Syst,Wuhan Inst Phy, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Tsinghua Univ, Grad Sch Shenzhen, Engn Lab Next Generat Power & Energy Storage Batt, Shenzhen 518055, Peoples R China 3.Taiyuan Univ Technol, Coll Mat Sci & Engn, Lab Green Energy Mat & Storage Syst, Taiyuan 030024, Shanxi, Peoples R China 4.Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, 1295 Dingxi Rd, Shanghai 200050, Peoples R China 5.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China
推荐引用方式 GB/T 7714	Huang, Yun-Hui,Liu, Jianjun,Kang, Litao,et al. Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity[J]. CHEM,2018,4(10):2463-2478.
APA	Huang, Yun-Hui.,Liu, Jianjun.,Kang, Litao.,Zeng, Rui.,Huang, Ying.,...&Liu, Yaojun.(2018).Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity.CHEM,4(10),2463-2478.
MLA	Huang, Yun-Hui,et al."Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity".CHEM 4.10(2018):2463-2478.