New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel

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	New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel
	Wang, Pu; Du, Shiyu; Huang, Qing; Shi, Weiqun; Yan, Yongde; Ji, Debin; Zhang, Yiming; Zhang, Milin
刊名	ELECTROCHEMISTRY COMMUNICATIONS
	2018
卷号	93 页码:180-182
关键词	Molten-salt Electronegativity Electrodes Energy
英文摘要	In this work, the electrochemical behavior of lanthanides (except promethium) on several active cathodes in LiCl-KCl molten salts was investigated. We have discovered that the reduction potentials of lanthanide alloys present a "bimodal effect". A numerical model was established based on the result of multiple linear regression analyses, which indicates that the reduction potentials are correlated with differences in atomic radii and differences in electronegativity. Employing the fitted formulae, which provide a preliminary model of the behavior of these elements in electrolysis-based pyroprocessing, the electrochemistry of both lanthanides and actinides on active metal cathodes could be reasonably estimated.
学科主题	Polymer Science
语种	英语
公开日期	2018-12-04
内容类型	期刊论文
源URL	[http://ir.nimte.ac.cn/handle/174433/17284]
专题	2018专题
推荐引用方式 GB/T 7714	Wang, Pu,Du, Shiyu,Huang, Qing,et al. New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel[J]. ELECTROCHEMISTRY COMMUNICATIONS,2018,93:180-182.
APA	Wang, Pu.,Du, Shiyu.,Huang, Qing.,Shi, Weiqun.,Yan, Yongde.,...&Zhang, Milin.(2018).New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel.ELECTROCHEMISTRY COMMUNICATIONS,93,180-182.
MLA	Wang, Pu,et al."New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel".ELECTROCHEMISTRY COMMUNICATIONS 93(2018):180-182.