An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid

doi:10.1016/j.ijhydene.2017.12.167

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	An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid
	He, Nan 1,2; Gong, Yafeng 2,3; Yang, Yidi 4; Wang, Yi 2; Qin, Chuanguang 1; Wang, Rumin 1; Liu, Jiehua 3; Qi, Tao 2
刊名	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
	2018-02-08
卷号	43 期号:6 页码:3216-3222
关键词	Ni-b Alloys Pd Electrocatalysts Formic Acid Oxidation Fuel Cells
ISSN号	0360-3199
DOI	10.1016/j.ijhydene.2017.12.167
文献子类	Article
英文摘要	The Pd@Ni-B/C catalysts were prepared by using Ni-B/C with different amounts of Ni-B alloys as supports. The structure, morphology and element valence state of these catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS), respectively. The electro-catalytic performance of these catalysts for formic acid oxidation was investigated using cyclic voltammetry (CV), chronoamperometry (CA) and CO stripping experiments. It was found that an appropriate amount of Ni-B alloys plays an important role in enhancing catalytic activity and resistance to CO poisoning and improving stability of Pd based catalysts, all of which imply that PdONi1.61B0.0199/C is promising for probable applications in direct formic acid fuel cell field. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
WOS关键词	Carbon Nanotubes Catalyst ; Reduced Graphene Oxide ; Fuel-cells ; Oxidation Reaction ; Hydrogen Storage ; Nanoparticles ; Performance ; Support ; Electrocatalysts ; Deactivation
WOS研究方向	Chemistry ; Electrochemistry ; Energy & Fuels
语种	英语
WOS记录号	WOS:000426225000013
资助机构	One Hundred Talent Program of Chinese Academy of Sciences ; 973 Program(2015CB251303)
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/24011]
专题	过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位	1.Northwestern Polytech Univ, Sch Nat & Appl Sci, Xian 710072, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China 4.Tongji Univ, Coll Environm Sci & Engn, Shanghai 200092, Peoples R China
推荐引用方式 GB/T 7714	He, Nan,Gong, Yafeng,Yang, Yidi,et al. An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2018,43(6):3216-3222.
APA	He, Nan.,Gong, Yafeng.,Yang, Yidi.,Wang, Yi.,Qin, Chuanguang.,...&Qi, Tao.(2018).An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,43(6),3216-3222.
MLA	He, Nan,et al."An effective Pd@Ni-B/C anode catalyst for electro-oxidation of formic acid".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 43.6(2018):3216-3222.