Upconversion 32Nb(2)O(5)-10La(2)O(3)-16ZrO(2) glass activated with Er3+/Yb3+ and dye sensitized solar cell application | |
Lia, Xiaoyu1; Li, Jiaying1,2; Li, Jianqiang1,3; Lin, Hong4; Li, Bo2 | |
刊名 | JOURNAL OF ADVANCED CERAMICS |
2017-12-01 | |
卷号 | 6期号:4页码:312-319 |
关键词 | Aerodynamic Levitation (Adl) Niobium Pentoxide Upconversion Rare Earth Concentration Solar Cell |
ISSN号 | 2226-4108 |
DOI | 10.1007/s40145-017-0243-3 |
文献子类 | Article |
英文摘要 | Er3+/Yb3+ codoped niobium pentoxide glasses were fabricated by the aerodynamic levitation (ADL) method with rapid cooling rate. All samples with various doping concentrations showed good upconversion luminescence properties under 980 nm laser excitation. The structure, transmittance spectrum, and luminescence properties of the samples were systemically investigated by XRD, UV-Vis-NIR spectrophotometer, and upconversion spectra. All transparent samples exhibited green and red upconversion emissions centered at 532, 547, and 670 nm. Experimental results showed that the sample codoped with 1 mol% Er3+/Yb3+ has the strongest upconversion emissions, and the increase of the doped Yb3+ concentration results in the increased red emission and reduced green emission. The logI-logP plot of green emission indicated that the green emissions reach the saturation at high pump power excitation, deviating from the low-power regime. After one-photon energy transfer (ET) process, I-4(11/2)+I-4(11/2)-> F-4(7/2)+I-4(15/2) process between the two neighboring Er3+ ions was responsible for the population of the S-4(3/2)/H-4(11/2) states. The niobium pentoxide codoped with Er-3+/Yb-3+ bulk glasses could be used in the dye sensitized solar cell (DSSC) to improve the efficiency. |
WOS关键词 | Near-infrared Light ; Nanocrystalline Phosphor ; Nanoparticles ; Ceramics ; Transparent ; Emission |
WOS研究方向 | Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000418405700004 |
资助机构 | National Natural Science Foundation of China(51671181 ; Beijing Natural Science Foundation(2152032) ; Science and Technology Plan of Shenzhen City(JCYJ20150827165038323) ; State Key Laboratory of New Ceramic and Fine Processing Tsinghua University(KF201417) ; Key Laboratory of Photochemical Conversion and Optoelectronic Materials (TIPC in CAS) ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201520) ; 51674232 ; 51471158) |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/23495] |
专题 | 过程工程研究所_研究所(批量导入) |
通讯作者 | Li, Jianqiang |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Tsinghua Univ, Grad Sch Shenzhen, Adv Mat Inst, Shenzhen 518055, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China |
推荐引用方式 GB/T 7714 | Lia, Xiaoyu,Li, Jiaying,Li, Jianqiang,et al. Upconversion 32Nb(2)O(5)-10La(2)O(3)-16ZrO(2) glass activated with Er3+/Yb3+ and dye sensitized solar cell application[J]. JOURNAL OF ADVANCED CERAMICS,2017,6(4):312-319. |
APA | Lia, Xiaoyu,Li, Jiaying,Li, Jianqiang,Lin, Hong,&Li, Bo.(2017).Upconversion 32Nb(2)O(5)-10La(2)O(3)-16ZrO(2) glass activated with Er3+/Yb3+ and dye sensitized solar cell application.JOURNAL OF ADVANCED CERAMICS,6(4),312-319. |
MLA | Lia, Xiaoyu,et al."Upconversion 32Nb(2)O(5)-10La(2)O(3)-16ZrO(2) glass activated with Er3+/Yb3+ and dye sensitized solar cell application".JOURNAL OF ADVANCED CERAMICS 6.4(2017):312-319. |
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