Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst

doi:10.1016/j.apsusc.2017.07.234

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	Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst
	Gao, Junjie 1; Zhang, Zailei 2,3; An, Xuebin 1; Zhang, Yi 1
刊名	APPLIED SURFACE SCIENCE
	2017-12-31
卷号	426 期号:DEC 页码:714-724
关键词	Cuo Sno2 Palladium Hollow
ISSN号	0169-4332
DOI	10.1016/j.apsusc.2017.07.234
文献子类	Article
英文摘要	We designed and synthesized CuO/SnO2/Pd hollow microboxes, which was developed based on pre pared Cu2O cubes coated Pd nanosheets, controlled oxidation of CU2O/Pd, and etching of Cu2O/CuO/Pd by SnCl4 solution. The catalytic property of the Cu2O, Cu2O/SnO2, Cu2O/Pd/SnO2, Cu2O/Pd, Cu2O/CuO/Pd, CuO/SnO2/Pd, CuO, and commercial catalyst for dimethyldichlorosilane synthesis via the Rochow reaction was investigated. As compared to control samples and commercial catalyst, the prepared CuO/Pd/SnO2 hollow microboxes exhibited much higher silicon conversion (76.6%), which is related to the synergistic effect between CuO, Pd and SnO2, and to the distinct catalyst hollow structure which allows the efficient transportation of the reactant molecules to the active component. (C) 2017 Elsevier B.V. All rights reserved.
WOS关键词	COPPER-BASED CATALYSTS ; DIMETHYLDICHLOROSILANE SYNTHESIS ; SOLVOTHERMAL SYNTHESIS ; ION BATTERIES ; MICROSPHERES ; PERFORMANCE ; NANOSTRUCTURES ; MICROPARTICLES ; OXIDATION ; SPHERES
WOS研究方向	Chemistry ; Materials Science ; Physics
语种	英语
WOS记录号	WOS:000413658200079
资助机构	National Natural Science Foundation of China(21006120 ; 51402299)
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/23398]
专题	过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位	1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China 3.Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Gao, Junjie,Zhang, Zailei,An, Xuebin,et al. Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst[J]. APPLIED SURFACE SCIENCE,2017,426(DEC):714-724.
APA	Gao, Junjie,Zhang, Zailei,An, Xuebin,&Zhang, Yi.(2017).Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst.APPLIED SURFACE SCIENCE,426(DEC),714-724.
MLA	Gao, Junjie,et al."Designed synthesis CuO hollow microboxes coated with Pd nanosheets and SnO2 nanoparticles as a highly efficient Rochow reaction catalyst".APPLIED SURFACE SCIENCE 426.DEC(2017):714-724.