Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot

doi:10.1039/c7ra08569a

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 材料生物技术研究中心

	Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot
	Zhang, Song 1,2; Xu, Chao 1,2; Zhai, Guoqing 1; Zhao, Mingliang 1; Xian, Mo 1; Jia, Yuxiang 1; Yu, Zongjiang 1; Liu, Fusheng 2; Jian, Fangfang 2; Sun, Weizhi 1
刊名	RSC ADVANCES
	2017
卷号	7 期号:75 页码:47539-47546
DOI	10.1039/c7ra08569a
文献子类	Article
英文摘要	A new type of bimetallic palladium and aluminum incorporated mobile crystalline materials (Pd-Al-MCM-41) as bifunctional catalysts has been hydrothermally synthesized. Characterization shows that these molecular materials exhibit an ordered mesoporous structure, high surface area and a good dispersion of palladium in the frame. The catalytic activity of the Pd-Al-MCM-41 for the dimerization-hydrogenation reaction system of beta-pinene in one pot has been systematically studied. Pd-0.5-Al-30-MCM-41 (SiO2/Al2O3 = 30, 0.5 wt% palladium content) was found to be the best catalyst which gave a dimer yield of up to 64.7%. It is worth noting that palladium shows a good synergic catalytic effect with aluminum in the dimerization reaction and enhances the dimerization yield. Furthermore, the bifunctional catalyst displayed a good activity over 4 runs.
WOS关键词	MCM-41 ; ISOMERIZATION ; POLYMERIZATION ; ZEOLITES ; ACIDITY ; FUELS
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000412977000037
资助机构	Natural Science Foundation of Shandong Province(ZR2016BQ39)
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/9731]
专题	青岛生物能源与过程研究所_材料生物技术研究中心
作者单位	1.Chinese Acad Sci, Qingdao Inst Biomass Energy & Bioproc Technol, Inst Biotechnol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Qingdao Univ Sci & Technol, Qingdao 266042, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Song,Xu, Chao,Zhai, Guoqing,et al. Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot[J]. RSC ADVANCES,2017,7(75):47539-47546.
APA	Zhang, Song.,Xu, Chao.,Zhai, Guoqing.,Zhao, Mingliang.,Xian, Mo.,...&Sun, Weizhi.(2017).Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot.RSC ADVANCES,7(75),47539-47546.
MLA	Zhang, Song,et al."Bifunctional catalyst Pd-Al-MCM-41 for efficient dimerization-hydrogenation of beta-pinene in one pot".RSC ADVANCES 7.75(2017):47539-47546.