CHARACTERIZATION OF SODIUM-CATIONS IN ZEOLITE OMEGA BY SOLID-STATE NA-23 NMR-SPECTROSCOPY

	CHARACTERIZATION OF SODIUM-CATIONS IN ZEOLITE OMEGA BY SOLID-STATE NA-23 NMR-SPECTROSCOPY
	YE, C ; WANG, J ; DING, D ; CHEN, T ; WANG, K ; DU, Y ; DENG, F ; LI, H
刊名	APPLIED MAGNETIC RESONANCE
	1994
卷号	6 期号:4 页码:537-547
ISSN号	0937-9347
文献子类	Article
英文摘要	Sodium cations localized at crystallographically distinct cation sites in the hydrated zeolite omega were characterized by various solid-state Na-23 NMR techniques, such as Na-23 MAS, H-1-Na-23 CP/MAS, Na-23 quadrupolar nutation and variable temperature NMR spectroscopy. In the Na-23 NMR spectrum of zeolite omega two signals were identified, a low-field Gaussian line at ca. -3 ppm (its quadrupole coupling constant was estimated approximately on the order of magnitude of 0.2 MHz) and a high-field quadrupole pattern with an isotropic chemical shift of -8 ppm and a quadrupole coupling constant of 2.3 MHz. The former signal is attributed to sodium cations in the 12-ring channels and the latter one to sodium cations in gmelinite cages of zeolite omega. The variable temperature NMR experiments reveal the interactions between the sodium cation and the adsorbed water molecules in zeolite omega. The sodium cations in the 12-ring channels are highly hydrated and so mobile as to average the H-1-Na-23 dipole interaction. Hence, these sodium cations give no contribution to the H-1-Na-23 cross polarization process. By contrast, the sodium cations in the gmelinite cages are less hydrated and more rigid. They are closely bonded not only to the adsorbed water molecules but also to the lattice oxygen of the gmelinite cages, which leads to an effective H-1-Na-23 polarization transfer.
WOS关键词	INTEGER QUADRUPOLAR NUCLEI ; DOUBLE-ROTATION NMR ; AL-27 MAS NMR ; CROSS-POLARIZATION ; NUTATION NMR ; TRANSITION ; SPECTRA ; SI-29 ; ATOMS
WOS研究方向	Physics ; Spectroscopy
语种	英语
出版者	SPRINGER VERLAG
WOS记录号	WOS:A1994NX13600005
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/12497]
专题	中国科学院武汉物理与数学研究所
作者单位	1.CHINESE ACAD SCI,WUHAN INST PHYS,NUCL MAGNET RESONANCE & MOLEC PHYS LAB,POB 71010,WUHAN 430071,PEOPLES R CHINA 2.NANKAI UNIV,DEPT CHEM,TIANJIN,PEOPLES R CHINA
推荐引用方式 GB/T 7714	YE, C,WANG, J,DING, D,et al. CHARACTERIZATION OF SODIUM-CATIONS IN ZEOLITE OMEGA BY SOLID-STATE NA-23 NMR-SPECTROSCOPY[J]. APPLIED MAGNETIC RESONANCE,1994,6(4):537-547.
APA	YE, C.,WANG, J.,DING, D.,CHEN, T.,WANG, K.,...&LI, H.(1994).CHARACTERIZATION OF SODIUM-CATIONS IN ZEOLITE OMEGA BY SOLID-STATE NA-23 NMR-SPECTROSCOPY.APPLIED MAGNETIC RESONANCE,6(4),537-547.
MLA	YE, C,et al."CHARACTERIZATION OF SODIUM-CATIONS IN ZEOLITE OMEGA BY SOLID-STATE NA-23 NMR-SPECTROSCOPY".APPLIED MAGNETIC RESONANCE 6.4(1994):537-547.