Direct Insight into Ethane Oxidative Dehydrogenation over Boron Nitrides

doi:10.1002/cctc.201700725

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	Direct Insight into Ethane Oxidative Dehydrogenation over Boron Nitrides
	Zhang, Bingsen 3; Huang, Rui 3; Su, Dang Sheng 1,3,4; Schloegl, Robert 1; Zheng, Anmin 2; Liu, Yuefeng 3; Zhang, Yajie 3; Shi, Wen 3; Wu, Kuang-Hsu 3; Wang, Jia 3
刊名	CHEMCATCHEM
	2017-09-08
卷号	9 期号:17 页码:3293-3297
关键词	Boron C-h Activation Dehydrogenation Ethylene Production Nitrides
DOI	10.1002/cctc.201700725
文献子类	Article
英文摘要	The ultimate objective of chemical conversion is to achieve 100% selectivity from catalysis, and this is also a prodigious challenge for the conversion of light paraffins into olefins, because it involves controlled activation of highly stable aliphatic C-H bonds. Herein, we show that metal-free boron nitride (BN) nanosheets not only enable the oxidative dehydrogenation of ethane to ethylene exclusively at near 10% conversion, but they also deliver a remarkable 60% selectivity at an ethane conversion of 78% and remain stable over 400h at 575 degrees C. Our operando infrared spectroscopy and O-18 isotope tracer study explicitly demonstrates that B-O(H) active sites are formed at the edges of BN through the aid of ethane, and the dehydrogenation circle is completed over these B-O sites by the assistance of O-2.
WOS关键词	H BOND ACTIVATION ; SELECTIVE OXIDATION ; ACTIVE OXYGEN ; N-BUTANE ; CATALYSTS ; PROPANE ; ALKANES ; NANOTUBES ; SPECTRUM ; OXIDE
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000409878300004
资助机构	National Natural Science Foundation (NSFC) of China(21133010 ; National Natural Science Foundation (NSFC) of China(21133010 ; "Strategic Priority Research Program" of the Chinese Academy of Sciences(XDA09030103) ; "Strategic Priority Research Program" of the Chinese Academy of Sciences(XDA09030103) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; 21473223 ; 21473223 ; 51221264 ; 51221264 ; 21261160487 ; 21261160487 ; 91545119) ; 91545119) ; National Natural Science Foundation (NSFC) of China(21133010 ; National Natural Science Foundation (NSFC) of China(21133010 ; "Strategic Priority Research Program" of the Chinese Academy of Sciences(XDA09030103) ; "Strategic Priority Research Program" of the Chinese Academy of Sciences(XDA09030103) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; 21473223 ; 21473223 ; 51221264 ; 51221264 ; 21261160487 ; 21261160487 ; 91545119) ; 91545119)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/11366]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Max Planck Gesell, Fritz Haber Inst, Faradayweg 4-6, D-14195 Berlin, Germany 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Energy Res Resources Div, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Bingsen,Huang, Rui,Su, Dang Sheng,et al. Direct Insight into Ethane Oxidative Dehydrogenation over Boron Nitrides[J]. CHEMCATCHEM,2017,9(17):3293-3297.
APA	Zhang, Bingsen.,Huang, Rui.,Su, Dang Sheng.,Schloegl, Robert.,Zheng, Anmin.,...&Wang, Jia.(2017).Direct Insight into Ethane Oxidative Dehydrogenation over Boron Nitrides.CHEMCATCHEM,9(17),3293-3297.
MLA	Zhang, Bingsen,et al."Direct Insight into Ethane Oxidative Dehydrogenation over Boron Nitrides".CHEMCATCHEM 9.17(2017):3293-3297.