Formation of an interaction complex of hemicucurbit 6 uril and ferrocene.

	Formation of an interaction complex of hemicucurbit 6 uril and ferrocene.
	Jin, Xian-Yi ; Zhao, Jiang-Lin ; Wang, Fang ; Cong, Hang ; Tao, Zhu
刊名	JOURNAL OF ORGANOMETALLIC CHEMISTRY
	2017
文献子类	期刊论文
英文摘要	The supramolecular interaction between hemicucurbit[6] uril (HemiQ[6]) and ferrocene is investigated using H-1 and C-13 NMR spectroscopy, cyclic voltammetry (CV), isothermal titration calorimetry (ITC) and quantum chemistry. By means of the H-1 NMR and C-13 NMR spectra, the host-guest interaction is confirmed by the slight shift in the resonance peaks of ferrocene. Cyclic voltammetry shows the diffusion current of ferrocene was enhanced with a slight improvement in the voltammetric behavior in the presence of HemiQ[6]. Isothermal titration calorimetry provides thermodynamic data for the host-guest interaction and an association constant of K-a = 4.9 x 10(4) L mol(-1) in a 1: 1 ratio has been obtained. Quantum chemistry suggests the encapsulation complex was stabilized by the formation of hydrogen bonding between the aromatic protons on the ferrocene guest molecule and the carbonyl groups on hemicucurbit[6] uril, and the electron transfer of the interaction complex is more easy than in free ferrocene.
URL标识	查看原文
语种	英语
内容类型	期刊论文
源URL	[http://ir.siat.ac.cn:8080/handle/172644/12027]
专题	深圳先进技术研究院_医工所
作者单位	JOURNAL OF ORGANOMETALLIC CHEMISTRY
推荐引用方式 GB/T 7714	Jin, Xian-Yi , Zhao, Jiang-Lin , Wang, Fang ,et al. Formation of an interaction complex of hemicucurbit 6 uril and ferrocene.[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2017.
APA	Jin, Xian-Yi , Zhao, Jiang-Lin , Wang, Fang , Cong, Hang ,& Tao, Zhu.(2017).Formation of an interaction complex of hemicucurbit 6 uril and ferrocene..JOURNAL OF ORGANOMETALLIC CHEMISTRY.
MLA	Jin, Xian-Yi ,et al."Formation of an interaction complex of hemicucurbit 6 uril and ferrocene.".JOURNAL OF ORGANOMETALLIC CHEMISTRY (2017).