Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP)

doi:10.1515/ract-2017-2803

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP)
	Li, RF ; Cao, XJ ; Zhao, HG ; Liu, CX ; Li, Z ; Wang, JH ; Zhang, L ; Li, QG
刊名	RADIOCHIMICA ACTA
	2018
卷号	106 期号:3 页码:239-247
关键词	3rd Phase-formation Dodecane-tributylphosphate Solutions Tributyl-phosphate Solvent-extraction Purex Process Separation Systems Actinides Diluent u(Vi)
ISSN号	0033-8230
DOI	10.1515/ract-2017-2803
文献子类	期刊论文
英文摘要	As an alternate extractant for spent fuel reprocessing, the radiolysis properties of TiAP should be systematically studied to evaluate the feasibility of using it in engineering scale. In this paper, the irradiation stability of TiAP was investigated by using the concept of radiolysis ratio and G value. It is found the extent of radiolysis would be increased with the increasing of absorbed doses, but decreased with the increasing of pre-equilibrium aqueous HNO3 concentration. Furthermore, the radiolysis products were analyzed qualitatively and quantitatively with gas, liquid and ion chromatograph, based on which the possible radiolysis mechanism of TiAP was also concluded.
语种	英语
WOS记录号	WOS:000425945100007
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/29119]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Li, RF 2.Cao, XJ 3.Zhao, HG 4.Liu, CX 5.Li, Z 6.Wang, JH 7.Zhang, L 8.Li, QG
推荐引用方式 GB/T 7714	Li, RF,Cao, XJ,Zhao, HG,et al. Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP)[J]. RADIOCHIMICA ACTA,2018,106(3):239-247.
APA	Li, RF.,Cao, XJ.,Zhao, HG.,Liu, CX.,Li, Z.,...&Li, QG.(2018).Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP).RADIOCHIMICA ACTA,106(3),239-247.
MLA	Li, RF,et al."Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP)".RADIOCHIMICA ACTA 106.3(2018):239-247.