Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms

doi:10.1002/anie.201701089

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms
	Wang, LB; Li, HL; Zhang, WB; Zhao, X; Qiu, JX; Li, AW; Zheng, XS; Hu, ZP; Si, R; Zeng, J
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017
卷号	56 期号:17 页码:4712-4718
关键词	Hydrolysis Metal-support Interactions Rhodium Single-atom Catalysts Vanadium Dioxide
ISSN号	1433-7851
DOI	10.1002/anie.201701089
文献子类	期刊论文
英文摘要	Supported metal nanocrystals have exhibited remarkable catalytic performance in hydrogen generation reactions, which is influenced and even determined by their supports. Accordingly, it is of fundamental importance to determine the direct relationship between catalytic performance and metal-support interactions. Herein, we provide a quantitative profile for exploring metal-support interactions by considering the highest occupied state in single-atom catalysts. The catalyst studied consisted of isolated Rh atoms dispersed on the surface of VO2 nanorods. It was observed that the activation energy of ammonia-borane hydrolysis changed when the substrate underwent a phase transition. Mechanistic studies indicate that the catalytic performance depended directly on the highest occupied state of the single Rh atoms, which was determined by the band structure of the substrates. Other metal catalysts, even with non-noble metals, that exhibited significant catalytic activity towards NH3BH3 hydrolysis were rationally designed by adjusting their highest occupied states.
语种	英语
WOS记录号	WOS:000398576000003
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/27461]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Wang, LB,Li, HL,Zhang, WB,et al. Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(17):4712-4718.
APA	Wang, LB.,Li, HL.,Zhang, WB.,Zhao, X.,Qiu, JX.,...&Zeng, J.(2017).Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(17),4712-4718.
MLA	Wang, LB,et al."Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.17(2017):4712-4718.