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A stable lead halide perovskite nanocrystals protected by PMMA
Li, Xiao; Xue, Zhenjie; Luo, Dan; Huang, Chuanhui; Liu, Lizhi; Qiao, Xuezhi; Liu, Cong; Song, Qian; Yan, Cong; Li, Yingchun
刊名SCIENCE CHINA-MATERIALS
2018-03-01
卷号61期号:3页码:363-370
英文摘要To enhance the stability in humidity is very crucial to hybrid organic-inorganic lead halide perovskites in a broad range of applications. This report describes a coating stratergy of perovskite nanocrystals via poly-methylmethacrylate-introduced ligand-assisted reprecipitation, using the interactions between the Pb cations on the surface of perovskite nanocrystals and the functional ester carbonyl groups in polymethylmethacrylate framework. The hydrophobic framework shields the open metal sites of hybrid organic-inorganic lead halide perovskites from being attacked by water, effectively retarding the diffusion of water into the perovskite nanocrystals. The as-prepared films demonstrate high resistance to heat and moisture. Additionally, the introduction of polymethylmethacrylate into ligand-assisted reprecipitation can effectively control the bulk precipitation and promote the stability of the perovskite solution.
WOS记录号WOS:000428198700003
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/38730]  
专题化学研究所_其它
推荐引用方式
GB/T 7714
Li, Xiao,Xue, Zhenjie,Luo, Dan,et al. A stable lead halide perovskite nanocrystals protected by PMMA[J]. SCIENCE CHINA-MATERIALS,2018,61(3):363-370.
APA Li, Xiao.,Xue, Zhenjie.,Luo, Dan.,Huang, Chuanhui.,Liu, Lizhi.,...&Wang, Tie.(2018).A stable lead halide perovskite nanocrystals protected by PMMA.SCIENCE CHINA-MATERIALS,61(3),363-370.
MLA Li, Xiao,et al."A stable lead halide perovskite nanocrystals protected by PMMA".SCIENCE CHINA-MATERIALS 61.3(2018):363-370.
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