Hydrogen Atom Abstraction from CH4 by Nanosized Vanadium Oxide Cluster Cations

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	Hydrogen Atom Abstraction from CH4 by Nanosized Vanadium Oxide Cluster Cations
	Wu, Xiao-Nan; Ding, Xun-Lei; Li, Zi-Yu; Zhao, Yan-Xia; He, Sheng-Gui
刊名	JOURNAL OF PHYSICAL CHEMISTRY C
	OCT 16 2014
卷号	118 期号:41 页码:24062-24071
英文摘要	Four cyanide-bridged bimetallic Ni(II)-Fe(III) complexes have been synthesized and characterized in order to find new molecular materials with interesting magnetic properties. One-dimensional complexes of pentacyanoferrite(III), [Ni(2,3,2-tet)Fe(Him)(CN)(5)]center dot 3H(2)O (1), [Ni(3,2,3-tet)][Fe(CN)(5)(Him)]center dot 2H(2)O (2), [Ni(3,2,3-tet)][Fe(CN)(5)(1-CH(3)im)]center dot 4H(2)O (3), and [NiL1][Fe(CN)(5)(1-CH(3)im)]center dot 3H(2)O (4) have been prepared and characterized by X-ray single-crystal structure analysis and magnetic measurements. All complexes possesses linear or zigzag chains of alternate [Ni(L')](2+) and [Fe(L)(CN)(5)](2-) units, which are linked by two trans/cis cyanide ligands of [Fe(L)(CN)(5)](2-). Magnetic studies reveal that they exhibit intermetallic ferromagnetic coupling and long-range antiferromagnetic ordering. The strength of the Ni(II)-Fe(III) magnetic coupling has been analyzed by comparison with the related cyanide-bridged Ni(II)-Fe(III) complexes. (C) 2014 Elsevier Ltd. All rights reserved.
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38653]
专题	化学研究所_其它
推荐引用方式 GB/T 7714	Wu, Xiao-Nan,Ding, Xun-Lei,Li, Zi-Yu,et al. Hydrogen Atom Abstraction from CH4 by Nanosized Vanadium Oxide Cluster Cations[J]. JOURNAL OF PHYSICAL CHEMISTRY C,OCT ,118(41):24062-24071.
APA	Wu, Xiao-Nan,Ding, Xun-Lei,Li, Zi-Yu,Zhao, Yan-Xia,&He, Sheng-Gui.(OCT ).Hydrogen Atom Abstraction from CH4 by Nanosized Vanadium Oxide Cluster Cations.JOURNAL OF PHYSICAL CHEMISTRY C,118(41),24062-24071.
MLA	Wu, Xiao-Nan,et al."Hydrogen Atom Abstraction from CH4 by Nanosized Vanadium Oxide Cluster Cations".JOURNAL OF PHYSICAL CHEMISTRY C 118.41(OCT ):24062-24071.