Visible-light-mediated oxidative demethylation of N-6-methyl adenines | |
Xie, Li-Jun1,3; Wang, Rui-Li1,3; Wang, Dong1; Liu, Li1,3; Cheng, Liang1,2,3 | |
刊名 | CHEMICAL COMMUNICATIONS |
2017-10-04 | |
卷号 | 53期号:77页码:10734-10737 |
英文摘要 | We report a simple protocol that affords oxidative demethylation of N-6-methyl groups in N-6-methyl adenines (m(6)A). The biologically compatible photocatalyst riboflavin prompts a highly selective C-H abstraction from N-6-methyl in adenines under the irradiation of a visible blue LED light, affording a novel and highly selective biomimetic demethylation of m(6)A and related N-methyl adenine analogues. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/41092] |
专题 | 化学研究所_分子识别与功能实验室 |
作者单位 | 1.Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci,BNLMS, Beijing 100190, Peoples R China 2.South China Univ Technol, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Xie, Li-Jun,Wang, Rui-Li,Wang, Dong,et al. Visible-light-mediated oxidative demethylation of N-6-methyl adenines[J]. CHEMICAL COMMUNICATIONS,2017,53(77):10734-10737. |
APA | Xie, Li-Jun,Wang, Rui-Li,Wang, Dong,Liu, Li,&Cheng, Liang.(2017).Visible-light-mediated oxidative demethylation of N-6-methyl adenines.CHEMICAL COMMUNICATIONS,53(77),10734-10737. |
MLA | Xie, Li-Jun,et al."Visible-light-mediated oxidative demethylation of N-6-methyl adenines".CHEMICAL COMMUNICATIONS 53.77(2017):10734-10737. |
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