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Progress in Homogeneous Catalytic Hydrogenation of CO2
Li Yong1; Wang Zheng2,3,4; Liu Qingbin1
刊名CHINESE JOURNAL OF ORGANIC CHEMISTRY
2017-08-01
卷号37期号:8页码:1978-1990
关键词Homogeneous Catalytic Hydrogenation Carbon Dioxide Organometallic Complexes
英文摘要In recent years, due to the rising of sustainable development strategies and concerns about global warming, chemists have pay more attention to the application of carbon dioxide (CO2) as a resource for chemical synthesis. Thereinto, in the research of the using of CO2, catalytic hydrogenation of CO2 is one of the momentous means for the utilization of CO2. The homogeneous catalytic reaction has the advantage of mild reaction condition, high activity and easy regulation of the catalytic system and so forth, so the homogeneous catalytic hydrogenation CO2 becomes to be a hot topic in utilization of CO2 resource, especially in the catalytic production of formic acid, formaldehyde, methanol and amine derivatives, it has extensive application prospects. In this paper, the recent progress in the research of homogeneously hydrogenated CO2 catalyzed by organometallic complexes is reviewed. It included that types and structures, activity and selectivity of homogeneous catalysts for the catalytic production of formic acid, formaldehyde, mathanol and as C-1 synthons, and the advance in the reaction mechanism of homogeneous catalytic hydrogenation of CO2.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/41073]  
专题化学研究所_工程塑料实验室
作者单位1.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Hebei, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Li Yong,Wang Zheng,Liu Qingbin. Progress in Homogeneous Catalytic Hydrogenation of CO2[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2017,37(8):1978-1990.
APA Li Yong,Wang Zheng,&Liu Qingbin.(2017).Progress in Homogeneous Catalytic Hydrogenation of CO2.CHINESE JOURNAL OF ORGANIC CHEMISTRY,37(8),1978-1990.
MLA Li Yong,et al."Progress in Homogeneous Catalytic Hydrogenation of CO2".CHINESE JOURNAL OF ORGANIC CHEMISTRY 37.8(2017):1978-1990.
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