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Tunable Self-Assembly and Morphology-Dependent Photoconductivity of a Donor-Acceptor-Structured Diruthenium Complex
Sun, Meng-Jia1,2; Zhang, Xinliang1,2; Zhong, Yu-Wu1,2; Zhan, Chuanlang1,2; Yao, Jiannian1,2
刊名INORGANIC CHEMISTRY
2016-12-19
卷号55期号:24页码:13007-13013
英文摘要A donor acceptor-structured diruthenium complex, 1(PF6)(4), that contains an electron-deficient bridging ligand and electron-rich distal diarylamines modified with long aliphatic chains has been synthesized. By varying the solvent environments and assembly conditions, we obtained three different self-assembled nanostructures of 1(PF6)(4), including zero-dimensional nanospheres, one-dimensional nanofibers, and thin films with interconnected nanowire networks. These structures were investigated by scanning electron microscopy, transmission electron microscopy, dynamic light scattering, X-ray diffraction, and atomic force microscopy (AFM) analysis. Conductive AFM analysis shows that the nanowire networks exhibit a high conductivity of 0.023 S/cm and an enhanced photoconductivity of 0.59 S/cm under visible light irradiation.
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/37997]  
专题化学研究所_光化学实验室
作者单位1.Chinese Acad Sci, CAS Key Lab Photochem, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Sun, Meng-Jia,Zhang, Xinliang,Zhong, Yu-Wu,et al. Tunable Self-Assembly and Morphology-Dependent Photoconductivity of a Donor-Acceptor-Structured Diruthenium Complex[J]. INORGANIC CHEMISTRY,2016,55(24):13007-13013.
APA Sun, Meng-Jia,Zhang, Xinliang,Zhong, Yu-Wu,Zhan, Chuanlang,&Yao, Jiannian.(2016).Tunable Self-Assembly and Morphology-Dependent Photoconductivity of a Donor-Acceptor-Structured Diruthenium Complex.INORGANIC CHEMISTRY,55(24),13007-13013.
MLA Sun, Meng-Jia,et al."Tunable Self-Assembly and Morphology-Dependent Photoconductivity of a Donor-Acceptor-Structured Diruthenium Complex".INORGANIC CHEMISTRY 55.24(2016):13007-13013.
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