Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O | |
Zhang, FY (Zhang, Fangyuan); Zhang, FF (Zhang, Fangfang); Qun, J (Qun, Jing); Pan, SL (Pan, Shilie); Yang, ZH (Yang, Zhihua); Jia, DZ (Jia, Dianzeng) | |
刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS |
2015 | |
卷号 | 17期号:16页码:10489-10496 |
ISSN号 | 1463-9076 |
DOI | 10.1039/c5cp00864f |
英文摘要 | Strontium borate Sr2B5O9(OH)center dot H2O (space group C2, No. 5) has been synthesized in high yields using a facile hydrothermal method. The UV-Vis-NIR diffuse reflectance spectrum shows that it has a wide transparency range extending from UV to NIR with the short-wavelength cut off edge below 190 nm. Second-harmonic generation (SHG) has been measured with a 1064 nm laser using the Kurtz and Perry technique, which shows that Sr2B5O9(OH)center dot H2O is phase matchable and the powder SHG effect is approximately 3 times that of KDP. It also has a high thermal stability up to 500 degrees C which has been identified by TG, DSC and variable-temperature PXRD. These properties make it possible for application as a UV nonlinear optical (NLO) material. Based on the electronic band structure, the optical refractive indices, birefringence, and SHG coefficients of Sr2B5O9(OH)center dot H2O are calculated, which are consistent with experiments. In addition, the electronic structure, SHG-weighted electron density and real-space atom-cutting analyses are performed to elucidate the origin of its NLO properties. |
WOS记录号 | WOS:000352707200021 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/5171] |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Zhang, FF (Zhang, Fangfang) |
作者单位 | 1.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, FY ,Zhang, FF ,Qun, J ,et al. Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2015,17(16):10489-10496. |
APA | Zhang, FY ,Zhang, FF ,Qun, J ,Pan, SL ,Yang, ZH ,&Jia, DZ .(2015).Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,17(16),10489-10496. |
MLA | Zhang, FY ,et al."Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 17.16(2015):10489-10496. |
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