ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges

doi:10.1039/c7dt03172f

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges
	Ma, RR (Ma, Ruru); Xu, DD (Xu, Dongdong); Yang, Y (Yang, Yun); Su, X (Su, Xin); Lei, BH (Lei, Binghua); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
刊名	DALTON TRANSACTIONS
	2017
卷号	46 期号:43 页码:14839-14846
ISSN号	1477-9226
DOI	10.1039/c7dt03172f
英文摘要	Two new isostructural rare-earth oxyborates ScMO(BO3) (M = Ca and Cd) with a three-dimensional (3D) cationic framework and parallel arranged [BO3] triangles have been synthesized by the flux method. In the 3D cationic framework, an interesting sandwich-like basic building unit (BBU) is constructed by two 1(infinity)[Ca(1) O-4](6-) chains and two 1(infinity)[Sc(1) O-4](5-) chains. ScMO(BO3) melt incongruently, which shows that title compounds can be grown by the flux method. The UV cut-off edges for ScCaO(BO3) and ScCdO(BO3) are 230 and 249 nm, respectively. In addition, the first-principles calculations are performed to gain further insights into the relationship between the microscopic electronic structures and associated optical properties
WOS记录号	WOS:000414775000019
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/5078]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
通讯作者	Yang, Y (Yang, Yun); Pan, SL (Pan, Shilie)
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Ma, RR ,Xu, DD ,Yang, Y ,et al. ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges[J]. DALTON TRANSACTIONS,2017,46(43):14839-14846.
APA	Ma, RR .,Xu, DD .,Yang, Y .,Su, X .,Lei, BH .,...&Pan, SL .(2017).ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges.DALTON TRANSACTIONS,46(43),14839-14846.
MLA	Ma, RR ,et al."ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges".DALTON TRANSACTIONS 46.43(2017):14839-14846.