Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface

doi:10.1021/acsnano.5b06666

	Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface
	Chang, SQ; Liu RC(刘润聪); Liu, RC; Wang, LC; Li M(李敏); Li, M; Deng, K; Zheng, QY; Zeng, QD
刊名	ACS NANO
	2016
卷号	10 期号:1 页码:342-348
关键词	structural transformation HPB network coronene cluster scanning tunneling microscopy guest inclusion
DOI	10.1021/acsnano.5b06666
通讯作者	李敏
文献子类	期刊论文
英文摘要	In the present work, we report the fabrication of regular coronene (COR) clusters on surfaces in ambient conditions in the two-dimensional network formed by hexaphenylbenzene derivatives (HPB) via structural transformation. HPB could form a stable snowflake network structure on the highly oriented pyrolytic graphite surface at the air solid interface. When COR molecules were introduced into the system, the HPB snowflake network could transform to honeycomb structures, and the COR heptamers were subsequently aggregated and entrapped into the cavity. Scanning tunneling microscopic was employed to monitor the assembly behavior of both HPB and HPB/COR at a submolecule scale level, and density functional theory calculations were utilized to reveal that the structural transformation and the entrapment are the energetically favorable. The pores formed from HPB might also give a clue to immobilizing some functional molecule clusters, like COR, to fabricate their ordered monolayer in ambient conditions, so as to obtain complex supramolecular surface structures.
WOS关键词	LIQUID-SOLID INTERFACE ; GUEST INCLUSION ; MANIPULATION ; ORGANIZATION ; ASSEMBLIES ; ADSORPTION ; MOLECULES ; AU(111) ; SYSTEMS
语种	英语
WOS记录号	WOS:000369115800035
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/260375]
专题	中国科学院高能物理研究所
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Chang, SQ,Liu RC,Liu, RC,et al. Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface[J]. ACS NANO,2016,10(1):342-348.
APA	Chang, SQ.,刘润聪.,Liu, RC.,Wang, LC.,李敏.,...&Zeng, QD.(2016).Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface.ACS NANO,10(1),342-348.
MLA	Chang, SQ,et al."Formation of Ordered Coronene Clusters in Template Utilizing the Structural Transformation of Hexaphenylbenzene Derivative Networks on Graphite Surface".ACS NANO 10.1(2016):342-348.