Metal-Organic Framework for Emulsifying Carbon Dioxide and Water

doi:10.1002/anie.201602150

	Metal-Organic Framework for Emulsifying Carbon Dioxide and Water
	Sang, XX; Zhang J(张静); Zheng LR(郑黎荣); Han, BX; Tan, XN; Luo, T; Zhang, BX; Kang, XC; Zhang, J; Zheng, L
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2016
卷号	55 期号:38 页码:11372-11376
关键词	CO2 emulsions H2O metal-organic frameworks superstructures
DOI	10.1002/anie.201602150
英文摘要	Forming emulsions of carbon dioxide (CO2) and water can largely expand the utility of CO2. Herein we propose for the first time the utilization of a metal-organic framework (MOF) for emulsifying CO2 and water. Owing to the hybrid composition, MOF particles can easily assemble at the CO2/water interface to create a rigid protective barrier around the dispersed droplet. The MOF-stabilized CO2 and water emulsion has exceptional stability compared to those emulsions stabilized by surfactants or other solids. Moreover, the CO2 and water emulsion stabilized by MOF is tunable due to the designable features of MOFs and adjustable character of CO2. Such a novel kind of emulsion composed of CO2, water, and MOF provides a facile route for constructing MOF superstructures with many advantages. The macroporous networks and hollow capsules of different kinds of MOFs have been successfully derived from CO2 and water emulsions.
语种	英语
WOS记录号	WOS:000383748900006
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/260330]
专题	高能物理研究所_多学科研究中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Sang, XX,Zhang J,Zheng LR,et al. Metal-Organic Framework for Emulsifying Carbon Dioxide and Water[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(38):11372-11376.
APA	Sang, XX.,张静.,郑黎荣.,Han, BX.,Tan, XN.,...&Liu, CC.(2016).Metal-Organic Framework for Emulsifying Carbon Dioxide and Water.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(38),11372-11376.
MLA	Sang, XX,et al."Metal-Organic Framework for Emulsifying Carbon Dioxide and Water".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.38(2016):11372-11376.