Modified Si nanowire/graphite-like carbon nitride core-shell photoanodes for solar water splitting
Wang, Xin; Zhou, Guofu; Chen ZH(陈志鸿); Meng QG(孟庆国); Li, Lin; Chen Zhen; Ning, Minghui; Yuan MZ(苑明哲); Zhang, Zhang; Jin, Mingliang
刊名Electrochemistry Communications
2018
卷号87页码:13-17
关键词Water splitting Si nanowires Graphite-like carbon nitride Core/shell nanostructure Copolymerization modification
ISSN号1388-2481
通讯作者Chen ZH(陈志鸿)
产权排序2
中文摘要Si nanowires (SiNWs) and graphite-like carbon nitride (g-C3N4) are highly promising materials for solar water splitting. In this work, n-type SiNWs (n-SiNWs) are obtained via metal-catalyzed electroless etching. To improve the photoelectrochemical performance of the n-SiNWs, g-C3N4is deposited on their surface as a coating layer (n-SiNW/g-C3N4). Furthermore, to increase the density of active sites in g-C3N4, barbituric acid (BA) is introduced into precursors before the layer deposition. The n-SiNW/g-C3N4photoanode shows a negative shift of the onset potential as compared to the bare n-SiNWs. Moreover, a 50% enhancement in the photocurrent density at 1.6 V vs. RHE is achieved on the BA-modified n-SiNW/g-C3N4as compared to the pristine n-SiNW/g-C3N4.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Electrochemistry
研究领域[WOS]Electrochemistry
关键词[WOS]PHOTOELECTROCHEMICAL HYDROGEN EVOLUTION ; VISIBLE-LIGHT ; H-2 EVOLUTION ; EFFICIENT ; ARRAYS ; PHOTOCATALYSTS ; PHOTOCATHODES ; NANOMATERIALS ; CATALYSIS ; SEAWATER
收录类别SCI ; EI
语种英语
WOS记录号WOS:000424295300004
内容类型期刊论文
源URL[http://ir.sia.cn/handle/173321/21468]  
专题沈阳自动化研究所_广州中国科学院沈阳自动化研究所分所
作者单位1.International Academy of Optoelectronics at Zhaoqing, South China Normal University, Guangdong Province, China
2.Shenyang Institute of Automation, Chinese Academy of Sciences, Guangzhou, 511458, China
3.National Center for International Research on Green Optoelectronics, South China Normal University, Guangzhou, 510006, China
4.Guangdong Provincial Key Laboratory of Optical Information Materials and Technology & Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, 510006, China
推荐引用方式
GB/T 7714
Wang, Xin,Zhou, Guofu,Chen ZH,et al. Modified Si nanowire/graphite-like carbon nitride core-shell photoanodes for solar water splitting[J]. Electrochemistry Communications,2018,87:13-17.
APA Wang, Xin.,Zhou, Guofu.,Chen ZH.,Meng QG.,Li, Lin.,...&Zhang, Yongguang.(2018).Modified Si nanowire/graphite-like carbon nitride core-shell photoanodes for solar water splitting.Electrochemistry Communications,87,13-17.
MLA Wang, Xin,et al."Modified Si nanowire/graphite-like carbon nitride core-shell photoanodes for solar water splitting".Electrochemistry Communications 87(2018):13-17.
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