Mineralogical alteration of thermally treated siderite in air: Mossbauer spectroscopy results | |
Pan, YX; Zhu, RX; Ping, JY | |
刊名 | CHINESE SCIENCE BULLETIN |
1999-09-01 | |
卷号 | 44期号:18页码:1712-1717 |
关键词 | siderite mienralogical phase transition thermally treated in air |
ISSN号 | 1001-6538 |
文献子类 | Article |
英文摘要 | Mineralogical alternation of thermally treated siderite in air atmosphere has been systematically analyzed by Mossbauer effects. It was preliminarily estimated from the area of subspectra that 4%, 39% and 62% of magnetite were formed at 410 degrees C, 490 degrees C and 510 degrees C respectively. After being incrementally heated at 530 degrees C the spectra consist of two sextets of Fe3O4. Sextet of gamma-Fe2O3 with hyperfine field of 50T was observed at 550 degrees C. Spectra at 580 degrees C consisted of two sextets with hyperfine fields caused by gamma-Fe2O3 and alpha-Fe2O3. Fe3O4 disappeared and the amount of gamma-Fe2O3 decreased, while the quantity of alpha-Fe2O3 increased to 34% and 77% at 640 degrees C and 690 degrees C, respectively. During the early stage of decomposition and oxidation, FeO was probably produced but quickly oxidized to magnetite and unidentified in our experiment. These results, in good agreement with the X-ray diffraction analyses and microscopic observation, provide an interpretation to anomalous magnetic property changes of siderite-bearing rock samples. |
WOS关键词 | DECOMPOSITION |
WOS研究方向 | Science & Technology - Other Topics |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000083584600020 |
内容类型 | 期刊论文 |
源URL | [http://ir.iggcas.ac.cn/handle/132A11/75304] |
专题 | 中国科学院地质与地球物理研究所 |
通讯作者 | Pan, YX |
作者单位 | 1.Chinese Acad Sci, Inst Geophys, Beijing 100101, Peoples R China 2.Beijing Univ Sci & Technol, Dept Phys Mat, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Pan, YX,Zhu, RX,Ping, JY. Mineralogical alteration of thermally treated siderite in air: Mossbauer spectroscopy results[J]. CHINESE SCIENCE BULLETIN,1999,44(18):1712-1717. |
APA | Pan, YX,Zhu, RX,&Ping, JY.(1999).Mineralogical alteration of thermally treated siderite in air: Mossbauer spectroscopy results.CHINESE SCIENCE BULLETIN,44(18),1712-1717. |
MLA | Pan, YX,et al."Mineralogical alteration of thermally treated siderite in air: Mossbauer spectroscopy results".CHINESE SCIENCE BULLETIN 44.18(1999):1712-1717. |
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