Mesh-Embedded Polysulfone/Sulfonated Polysulfone Supported Thin Film Composite Membranes for Forward Osmosis
Zhao, Yuntao1,2; Wang, Xiao1; Ren, Yiwei1; Pei, Desheng1
刊名ACS APPLIED MATERIALS & INTERFACES
2018-01-24
卷号10期号:3页码:2918-2928
关键词sulfonated polysulfone forward osmosis mesh-embedded substrate thin film composite membrane structural parameter
ISSN号1944-8244
DOI10.1021/acsami.7b15309
英文摘要In this work, mesh-embedded polysulfone (PSU)/sulfonated polysulfone (sPSU) supported thin film composite (TFC) membranes were developed for forward osmosis (FO). The robust mesh integrated in PSU/sPSU sublayer imparts impressive mechanical durability. The blending of hydrophilic sPSU in PSU sublayer affects the hydrophilicity, porosity, pore structure, and pore size of mesh-embedded PSU/sPSU substrates, and the total thickness, cross-linking degree, and roughness of the corresponding TFC-FO membrane active layers. An appropriate incorporation of sPSU not only significantly decreases the structural parameter, S of the mesh-embedded substrate to 220 mu m, which is the lowest reported value for fabric backed FO membrane, but also optimizes the permselectivity of the formed active layer. Regarding the osmosis performance, TFC membranes with sPSU modified substrates gain a higher water flux (J(w)) while keeping the specific reverse salt flux (J(s)/J(w)) low. The optimal TFC-FO membrane has a J(w) of 31.76 LMH with J(s)/J(w) of 0.19 g/L in FO mode when using deionized water feed and 1 M NaCl draw solution. This paper is practical for developing TFC-FO membrane on hydrophilic support membrane materials.
资助项目National Natural Science Foundation of China[51503205] ; National Natural Science Foundation of China[51478452] ; Chinese Academy of Sciences "Light of West China" Program ; Three Hundred Leading Talents in Scientific and Technological Innovation Program of Chongqing[CSTCCXLJRC201714] ; Key Application and Development Program of Chongqing Science and Technology Commission[cstc2014yykfC20004]
WOS研究方向Science & Technology - Other Topics ; Materials Science
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000423496500083
内容类型期刊论文
源URL[http://119.78.100.138/handle/2HOD01W0/6246]  
专题微纳制造与系统集成研究中心
中国科学院重庆绿色智能技术研究院
环境与健康研究中心
通讯作者Ren, Yiwei; Pei, Desheng
作者单位1.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Zhao, Yuntao,Wang, Xiao,Ren, Yiwei,et al. Mesh-Embedded Polysulfone/Sulfonated Polysulfone Supported Thin Film Composite Membranes for Forward Osmosis[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(3):2918-2928.
APA Zhao, Yuntao,Wang, Xiao,Ren, Yiwei,&Pei, Desheng.(2018).Mesh-Embedded Polysulfone/Sulfonated Polysulfone Supported Thin Film Composite Membranes for Forward Osmosis.ACS APPLIED MATERIALS & INTERFACES,10(3),2918-2928.
MLA Zhao, Yuntao,et al."Mesh-Embedded Polysulfone/Sulfonated Polysulfone Supported Thin Film Composite Membranes for Forward Osmosis".ACS APPLIED MATERIALS & INTERFACES 10.3(2018):2918-2928.
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