Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides

doi:10.1002/cjoc.201600801

	Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides
	Li, Xiaofang 1,2; Jia, Xiuquan 1; Ma, Jiping 1; Xu, Yongming 1,2; Huang, Yizheng 1; Xu, Jie 1
刊名	CHINESE JOURNAL OF CHEMISTRY
	2017-06-01
卷号	35 页码:984-990
关键词	Catalysis Alkali Manganese Oxides 5-hydroxymethylfurfural Ammoxidation 2 5-furandicarboxamide
DOI	10.1002/cjoc.201600801
英文摘要	2,5-Furandicarboxamide was firstly synthesized in yield of 85% via catalytic oxidative amidation of 5-hydroxymethylfurfural with aqueous NH3 over alkali manganese oxides of alpha-MnO2/NaxMnO2. The intermediates of 5-hydroxymethyl-furonitrile, 2,5-dicyanofuran, and 5-cyano-2-furancarboxamide were verified and their reactivities were further examined. The kinetic analysis results showed that the transformation of intermediate product of 5-cyano-2-furancarboxamide to 2,5-furan-dicarboxamide is a slower step, which is closely relative to the reaction temperature and basicity of catalyst.
语种	英语
WOS记录号	WOS:000404029500032
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/152129]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Xiaofang,Jia, Xiuquan,Ma, Jiping,et al. Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35:984-990.
APA	Li, Xiaofang,Jia, Xiuquan,Ma, Jiping,Xu, Yongming,Huang, Yizheng,&Xu, Jie.(2017).Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides.CHINESE JOURNAL OF CHEMISTRY,35,984-990.
MLA	Li, Xiaofang,et al."Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides".CHINESE JOURNAL OF CHEMISTRY 35(2017):984-990.