ScroBiculate sub-10 nm nanocavity arrays as effective sers substrate for the trace determination of 3,3 ',4,4 '- Polychlorinated biphenyls

doi:10.1016/j.apsusc.2016.12.132

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	ScroBiculate sub-10 nm nanocavity arrays as effective sers substrate for the trace determination of 3,3 ',4,4 '- Polychlorinated biphenyls
	Xu, Wei 1; Zhu, Xiaoguang ; Chu, Zhaoqin ; Wang, Zhaoming ; Xiao, Zhiyuan ; Huang, Zhulin
刊名	APPLIED SURFACE SCIENCE
	2017-03-31
卷号	399 期号:无页码:711-715
关键词	Nanocavity Array Sub-10 Nm Surface Enhanced Raman Scattering Trace Determination Polychlorinated Biphenyls
DOI	10.1016/j.apsusc.2016.12.132
文献子类	Article
英文摘要	This work presents a convenient method to fabricate large-area 'scrobiculate sub-10 nm Ag nanocavity arrays (NCA) through a facile replication and deposition process. Periodical cone-shaped NCA were constructed on the composite multi-layered noble metal film with cavity diameters abridged to the sub-10 nm scale. The resultant Ag NCA exhibited excellent SERS characteristic for Rhodamine 6G (R6G) and achieved a high enhancement factor of 3 x 10(9). The enhancement was found to be quantitatively related to the concentration of the R6G probe solutions. The enhancement characteristic was testified via a Raman mapping across a 50 x 50 mu m area on the substrate surface and achieved high homogeneity within the territory. For the SERS determination of Polychlorinated Biphenyls (PCBs), the surface of the NCA was modified with thiolated beta-Cyclodextrin (HS-beta-CD) and was thus functionalized as an incubation host for the PCBs molecules. Results suggest that the as-fabricated substrates show great potential in the SERS determination of the PCBs. (C) 2016 Elsevier B.V. All rights reserved.
WOS关键词	ENHANCED RAMAN-SPECTROSCOPY ; CAVITY ARRAYS ; NANOPARTICLES ; FILM ; PERFORMANCE ; SCATTERING ; PLASMONS ; GAPS
WOS研究方向	Chemistry ; Materials Science ; Physics
语种	英语
WOS记录号	WOS:000393001700082
资助机构	National Key Basic Research Program of China(2013CB934304) ; National Key Basic Research Program of China(2013CB934304) ; National Key Basic Research Program of China(2013CB934304) ; National Key Basic Research Program of China(2013CB934304) ; Natural Science Foundation of China(11274312 ; Natural Science Foundation of China(11274312 ; Natural Science Foundation of China(11274312 ; Natural Science Foundation of China(11274312 ; 10804112 ; 10804112 ; 10804112 ; 10804112 ; 51301162 ; 51301162 ; 51301162 ; 51301162 ; 51101151) ; 51101151) ; 51101151) ; 51101151) ; National Key Basic Research Program of China(2013CB934304) ; National Key Basic Research Program of China(2013CB934304) ; National Key Basic Research Program of China(2013CB934304) ; National Key Basic Research Program of China(2013CB934304) ; Natural Science Foundation of China(11274312 ; Natural Science Foundation of China(11274312 ; Natural Science Foundation of China(11274312 ; Natural Science Foundation of China(11274312 ; 10804112 ; 10804112 ; 10804112 ; 10804112 ; 51301162 ; 51301162 ; 51301162 ; 51301162 ; 51101151) ; 51101151) ; 51101151) ; 51101151)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/32814]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanostruct, Hefei 230031, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Xu, Wei,Zhu, Xiaoguang,Chu, Zhaoqin,et al. ScroBiculate sub-10 nm nanocavity arrays as effective sers substrate for the trace determination of 3,3 ',4,4 '- Polychlorinated biphenyls[J]. APPLIED SURFACE SCIENCE,2017,399(无):711-715.
APA	Xu, Wei,Zhu, Xiaoguang,Chu, Zhaoqin,Wang, Zhaoming,Xiao, Zhiyuan,&Huang, Zhulin.(2017).ScroBiculate sub-10 nm nanocavity arrays as effective sers substrate for the trace determination of 3,3 ',4,4 '- Polychlorinated biphenyls.APPLIED SURFACE SCIENCE,399(无),711-715.
MLA	Xu, Wei,et al."ScroBiculate sub-10 nm nanocavity arrays as effective sers substrate for the trace determination of 3,3 ',4,4 '- Polychlorinated biphenyls".APPLIED SURFACE SCIENCE 399.无(2017):711-715.