Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone

	Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone
	Wang, Aiqin 1,2; Li, Guangyi 2; Yang, Xiaofeng 2; Cong, Yu 2; Wang, Xiaodong 2; Li, Ning 1,2; Xu, Jilei 2; Zhang, Tao 1,2
刊名	ACS CATALYSIS
	2017-09-01
卷号	7 期号:9 页码:5880-5886
关键词	lignocellulose diesel and jet fuels angelica lactone aldol condensation hydrodeoxygenation
英文摘要	A route was developed for the synthesis of diesel and jet fuel range C-9 and C-10 alkanes with furfural and angelica lactone, which can be obtained from hemicellulose and cellulose. It was found that angelica lactone is more reactive than levulinic acid or its other derivates in the aldol condensation with furfural. Among the investigated catalysts, Mn2O3 was found to be the most active and was very stable for the aldol condensation of furfural and angelica lactone. Over Mn2O3, a high carbon yield of C-10 oxygenates (about 96%) can be achieved by the aldol condensation of furfural and angelica lactone under mild conditions (353 K, 4 h). By the hydrogenation and hydrodeoxygenation of the aldol condensation product over the Pd/C and Pd-FeOx/SiO2 catalysts, high carbon yields (similar to 96%) of C-9 and C-10 alkanes were obtained.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	WOODY BIOMASS SOLIDS ; HIGH-QUALITY DIESEL ; GAMMA-VALEROLACTONE ; CATALYTIC CONVERSION ; LIGNOCELLULOSIC BIOMASS ; TRANSPORTATION FUELS ; BIMETALLIC CATALYSTS ; ALDOL-CONDENSATION ; LIQUID ALKANES ; LEVULINIC ACID
收录类别	SCI
语种	英语
WOS记录号	WOS:000410005700036
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/150040]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wang, Aiqin,Li, Guangyi,Yang, Xiaofeng,et al. Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone[J]. ACS CATALYSIS,2017,7(9):5880-5886.
APA	Wang, Aiqin.,Li, Guangyi.,Yang, Xiaofeng.,Cong, Yu.,Wang, Xiaodong.,...&Zhang, Tao.(2017).Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone.ACS CATALYSIS,7(9),5880-5886.
MLA	Wang, Aiqin,et al."Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone".ACS CATALYSIS 7.9(2017):5880-5886.