Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes

	Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes
	Zhou, Xukai 1,2; Kong, Lingheng 1,2; Liu, Bingxian 3; Wang, Fen 2; Li, Xingwei 2
刊名	CHEMICAL COMMUNICATIONS
	2017-09-21
卷号	53 期号:74 页码:10326-10329
英文摘要	Rhodium(III)-catalyzed mild benzylic alpha-fluoroalkenylation of 8-methyl-quinolines with gem-difluorostyrenes has been developed. This reaction occurred via C-H activation and C-F cleavage and is applicable to a wide range of substrates, leading to the synthesis of Z-alkenyl fluorides under mild and redox-neutral conditions with high regio- and stereoselectivity.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	C-H BONDS ; C(SP(3))-H BONDS ; INTERMOLECULAR AMIDATION ; 4+1 ANNULATION ; ACTIVATION ; CATALYSIS ; 8-METHYLQUINOLINES ; FUNCTIONALIZATION ; ARYLATION ; ALKYLATION
收录类别	SCI
语种	英语
WOS记录号	WOS:000410942000020
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/150022]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Xukai,Kong, Lingheng,Liu, Bingxian,et al. Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes[J]. CHEMICAL COMMUNICATIONS,2017,53(74):10326-10329.
APA	Zhou, Xukai,Kong, Lingheng,Liu, Bingxian,Wang, Fen,&Li, Xingwei.(2017).Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes.CHEMICAL COMMUNICATIONS,53(74),10326-10329.
MLA	Zhou, Xukai,et al."Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes".CHEMICAL COMMUNICATIONS 53.74(2017):10326-10329.