Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent

	Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent
	Xu, Jie 2; Shi, Song 2; Liu, Meng 1,2; Zhao, Li 1,2; Wang, Min 2; Chen, Chen 2; Gao, Jin 2
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2017-09-19
卷号	12 期号:18 页码:2404-2409
关键词	alcohol cobalt hydrocarbon solvent hydrophobic oxidation
英文摘要	A hydrophobic cobalt catalyst was synthesized and proved to be effective in alcohol oxidation under the assistance of hydrocarbon solvent with oxygen as the terminal oxidant. A series of catalysts with different water contact angles was applied to investigate the hydrophobic effect. Further insight into the reaction process was gained by reaction kinetics, isotopic effect, etc. It showed that the hydrocarbon solvent participated in the alcohol oxidation, and with the aid of the in situ generated free radicals, the -C-H bond was smoothly activated and the alcohol was converted to carbonyl compounds. The hydrophobic effect promoted the alcohol oxidation by affecting the solvent oxidation.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	SELECTIVE AEROBIC OXIDATION ; BASE-FREE CONDITIONS ; OXIDE NANOPARTICLES ; ALIPHATIC-ALCOHOLS ; BENZYLIC ALCOHOLS ; DEHYDROGENATION ; WETTABILITY ; CHEMISTRY ; EFFICIENT ; COMPLEXES
收录类别	SCI
语种	英语
WOS记录号	WOS:000411081300016
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149927]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Xu, Jie,Shi, Song,Liu, Meng,et al. Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(18):2404-2409.
APA	Xu, Jie.,Shi, Song.,Liu, Meng.,Zhao, Li.,Wang, Min.,...&Gao, Jin.(2017).Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent.CHEMISTRY-AN ASIAN JOURNAL,12(18),2404-2409.
MLA	Xu, Jie,et al."Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent".CHEMISTRY-AN ASIAN JOURNAL 12.18(2017):2404-2409.