Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones

	Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones
	Liu, Tingting 1,3; Chai, Huining 1,3; Wang, Liandi 1; Yu, Zhengkun 1,2
刊名	ORGANOMETALLICS
	2017-08-14
卷号	36 期号:15 页码:2914-2921
英文摘要	Dinuclear ruthenium(II)-NNN complexes were efficiently assembled by means of coordinatively unsaturated 16-electron mononuclear ruthenium(II)-pyrazolyl-imidazolyl-pyridine complex and 4,4'-linked bipyridine ligands. The diruthenium(II)-NNN complex assembled through 4,4'-(CH2)(3)-bipyridine exhibited exceptionally high catalytic activity for the transfer hydrogenation (TH) of ketones in refluxing 2-propanol and reached TOF values up to 1.4 x 10(7) h(-1), demonstrating a remarkable cooperative effect from the ruthenium(II)-NNN functionalities.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Inorganic & Nuclear ; Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	ASYMMETRIC TRANSFER HYDROGENATION ; PYRAZOLYL-IMIDAZOLYL LIGAND ; HETEROMETALLIC COMPLEXES ; METAL-COMPLEXES ; NNN LIGAND ; BEARING ; OXIDATION ; OXYGEN ; WATER ; COOPERATIVITY
收录类别	SCI
语种	英语
WOS记录号	WOS:000407869100025
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149821]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Tingting,Chai, Huining,Wang, Liandi,et al. Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones[J]. ORGANOMETALLICS,2017,36(15):2914-2921.
APA	Liu, Tingting,Chai, Huining,Wang, Liandi,&Yu, Zhengkun.(2017).Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones.ORGANOMETALLICS,36(15),2914-2921.
MLA	Liu, Tingting,et al."Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones".ORGANOMETALLICS 36.15(2017):2914-2921.