Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation

	Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
	Zhang, Zailei 4; Zhu, Yihan 5; Asakura, Hiroyuki 1,6; Zhang, Bin 4; Zhang, Jiaguang 4; Zhou, Maoxiang 3; Han, Yu 2,5; Tanaka, Tsunehiro 1,6; Wang, Aiqin 3; Zhang, Tao 3
刊名	NATURE COMMUNICATIONS
	2017-07-27
卷号	8
英文摘要	Single-atom metal catalysts offer a promising way to utilize precious noble metal elements more effectively, provided that they are catalytically active and sufficiently stable. Herein, we report a synthetic strategy for Pt single-atom catalysts with outstanding stability in several reactions under demanding conditions. The Pt atoms are firmly anchored in the internal surface of mesoporous Al2O3, likely stabilized by coordinatively unsaturated pentahedral Al3+ centres. The catalyst keeps its structural integrity and excellent performance for the selective hydrogenation of 1,3-butadiene after exposure to a reductive atmosphere at 200 degrees C for 24 h. Compared to commercial Pt nanoparticle catalyst on Al2O3 and control samples, this system exhibits significantly enhanced stability and performance for n-hexane hydro-reforming at 550 degrees C for 48 h, although agglomeration of Pt single-atoms into clusters is observed after reaction. In CO oxidation, the Pt single-atom identity was fully maintained after 60 cycles between 100 and 400 degrees C over a one-month period.
WOS标题词	Science & Technology
类目[WOS]	Multidisciplinary Sciences
研究领域[WOS]	Science & Technology - Other Topics
关键词[WOS]	METAL-SUPPORT INTERACTIONS ; ATOMICALLY DISPERSED PALLADIUM ; WATER-GAS SHIFT ; PLATINUM NANOPARTICLES ; CERIA CATALYSTS ; N-HEXANE ; ELECTROCHEMICAL REACTIONS ; GOLD NANOPARTICLES ; ACTIVE-SITES ; SURFACE
收录类别	SCI
语种	英语
WOS记录号	WOS:000406360300001
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149793]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Kyoto Univ, ESICB, Kyoto 6158245, Japan 2.King Abdullah Univ Sci & Technol, Phys Sci & Engn Div, KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Natl Univ Singapore, Dept Chem & Biomol Engn, 4 Engn Dr 4, Singapore 117585, Singapore 5.King Abdullah Univ Sci & Technol, Phys Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia 6.Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Kyoto 6158510, Japan
推荐引用方式 GB/T 7714	Zhang, Zailei,Zhu, Yihan,Asakura, Hiroyuki,et al. Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation[J]. NATURE COMMUNICATIONS,2017,8.
APA	Zhang, Zailei.,Zhu, Yihan.,Asakura, Hiroyuki.,Zhang, Bin.,Zhang, Jiaguang.,...&Yan, Ning.(2017).Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation.NATURE COMMUNICATIONS,8.
MLA	Zhang, Zailei,et al."Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation".NATURE COMMUNICATIONS 8(2017).