In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O

	In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O
	Xu, Jie 1; Wang, Tianlong 1,2; Ma, Hong 1; Gao, Jin 1; Wang, Xinhong 2; Sun, Yuxia 1,3; Luo, Yang 1,3; Zhang, Shujing 1,3
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2017-11-02
卷号	12 期号:21 页码:2790-2793
关键词	dual-metal fabrication organic-inorganic hybrids photocatalysis zeolitic imidazolate frameworks
英文摘要	We successfully fabricate a well-defined inorganic/organic hybrid Cu2O@Cu/Co-ZIF (ZIF = zeolitic imidazolate frameworks) by use of growth of dual-metal Cu/Co-ZIF on the obtained Cu2O hollow spheres. The key point of the strategy is coupling the in situ self-sacrificing template. Cu2O and the coordination of metal ions (Cu+ and Co2+) with 2-methylimidazole. This new hybrid was characterized by powder X-ray diffraction, (scanning) transmission electron microscopy, energy-dispersive spectroscopy mapping, in situ FT-IR spectroscopy, UV/Vis diffuse reflection spectroscopy, N-2 sorption measurements, and electron spin resonance. It was evidenced that Cu/Co-ZIF nanocrystals have been assembled to continuous shells surrounding the Cu2O cores as well as in the voids between layers and inner pores. Cu2O@Cu/Co-ZIF exhibits visible light responsiveness and holds potential as narrow band gap semiconductor and visible photocatalyst.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	METAL-ORGANIC FRAMEWORK ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; CORE-SHELL ; THERMAL-CONVERSION ; NANOPOROUS CARBONS ; HIGH-PERFORMANCE ; FACILE SYNTHESIS ; NANOPARTICLES ; SELECTIVITY ; CATALYSIS
收录类别	SCI
语种	英语
WOS记录号	WOS:000414338400003
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149771]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Dalian Polytech Univ, Sch Text & Mat Engn, Dalian 116034, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Xu, Jie,Wang, Tianlong,Ma, Hong,et al. In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(21):2790-2793.
APA	Xu, Jie.,Wang, Tianlong.,Ma, Hong.,Gao, Jin.,Wang, Xinhong.,...&Zhang, Shujing.(2017).In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O.CHEMISTRY-AN ASIAN JOURNAL,12(21),2790-2793.
MLA	Xu, Jie,et al."In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O".CHEMISTRY-AN ASIAN JOURNAL 12.21(2017):2790-2793.