Two-Dimensional Mesoporous Carbon Doped with Fe-N Active Sites for Efficient Oxygen Reduction

	Two-Dimensional Mesoporous Carbon Doped with Fe-N Active Sites for Efficient Oxygen Reduction
	Ye, Yifan 2,3; Li, Haobo 2,3; Cai, Fan 2,3; Yan, Chengcheng 2,3; Si, Rui 4; Miao, Shu 2; Li, Yanshuo 1; Wang, Guoxiong 2; Bao, Xinhe 2
刊名	ACS CATALYSIS
	2017-11-01
卷号	7 期号:11 页码:7638-7646
关键词	zeolitic imidazolate framework-7 oxygen reduction reaction self-assembly 3D-to-2D transformation iron-nitrogen sites
英文摘要	Iron-nitrogen (Fe-N) sites confined within carbon are highly active to catalyze the oxygen reduction reaction (ORR). The mesoporous structure of carbon facilitates the mass transport and availability to the Fe-N sites during the ORR; however, the construction of mesoporous carbon architecture with highly exposed and accessible Fe-N active sites remains challenging. Herein, 3D-to-2D transformation of zeolitic imidazolate frame-work-7 (ZIF-7) was successfully achieved via convenient impregnation in ammonium ferric citrate aqueous solution. After pyrolysis, isolated Fe-N sites are generated and confined within highly mesoporous carbon without using any additional modulator or template. The optimal Fe-N catalyst exhibits excellent performance toward ORR in alkaline medium, exceeding commercial 40% Pt/C catalyst in terms of activity, stability, and methanol resistance.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	METAL-ORGANIC FRAMEWORKS ; FUNCTIONALIZED GRAPHITIC MATERIALS ; C CATALYSTS ; TRANSITION-METALS ; HIGHLY EFFICIENT ; ELECTROCATALYSTS ; EVOLUTION ; NITROGEN ; IRON ; COBALT
收录类别	SCI
语种	英语
WOS记录号	WOS:000414724700029
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149685]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China 2.Acad Sinica, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis,CAS Ctr Excellence Nanosc, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
推荐引用方式 GB/T 7714	Ye, Yifan,Li, Haobo,Cai, Fan,et al. Two-Dimensional Mesoporous Carbon Doped with Fe-N Active Sites for Efficient Oxygen Reduction[J]. ACS CATALYSIS,2017,7(11):7638-7646.
APA	Ye, Yifan.,Li, Haobo.,Cai, Fan.,Yan, Chengcheng.,Si, Rui.,...&Bao, Xinhe.(2017).Two-Dimensional Mesoporous Carbon Doped with Fe-N Active Sites for Efficient Oxygen Reduction.ACS CATALYSIS,7(11),7638-7646.
MLA	Ye, Yifan,et al."Two-Dimensional Mesoporous Carbon Doped with Fe-N Active Sites for Efficient Oxygen Reduction".ACS CATALYSIS 7.11(2017):7638-7646.