Preparation of carbon nanodots capped by polyethylene glycol as a multifunctional sensor for temperature and paracetamol | |
Xue, Fangfang2,3; You, Jinmao1,2,3![]() | |
刊名 | ANALYTICAL METHODS
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2017-08-21 | |
卷号 | 9期号:31页码:4533-4538 |
英文摘要 | In this paper, a simple and green preparative strategy for synthesizing carbon nanodots (CNDs) is developed by a one-pot hydrothermalmethod, using ascorbic acid (AA) as the carbon source and polyethylene glycol (PEG) with a molecular weight of 1500 as the surface modification agent. Through changing the amount ratio of PEG-1500 to AA in the synthesis, we can obtain PEG-CNDs with different functions. For example, due to the thermosensitivity of PEG-1500, the as-prepared PEG1-CNDs exhibit unique temperature sensitivity when the mass ratio of PEG-1500 to AA is 24 : 1. A reversible change of PEG1-CNDs from the solid state to transparent solution with increasing temperature can be repeated several times. The optical transmittance signal of PEG1-CNDs linearly responds to temperature in the range of 20-65 degrees C. Besides, while the amount ratio of PEG-1500 to AA is 12 : 1, the obtained PEG2-CNDs lose thermal sensitivity and form a stable and fluorescent solution at room temperature. The emission of PEG2-CNDs can be quenched by Fe3+, while with the addition of paracetamol (PAR), the fluorescence is recovered because of forming chelates between Fe3+ and PAR. Under the optimized conditions, the linear range of PAR obtained is 0.03-30 mM with a detection limit of 13 nM. Finally, the proposed method is successfully applied to detect PAR in human serum and urine samples with satisfactory recoveries. |
WOS标题词 | Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine ; Technology |
类目[WOS] | Chemistry, Analytical ; Food Science & Technology ; Spectroscopy |
研究领域[WOS] | Chemistry ; Food Science & Technology ; Spectroscopy |
关键词[WOS] | INJECTION SPECTROPHOTOMETRIC DETERMINATION ; ONE-STEP SYNTHESIS ; FLOW-INJECTION ; DOTS ; ACETAMINOPHEN ; ELECTRODE ; PHARMACEUTICALS ; HYDROLYSIS ; LIPOSOMES ; GRAPHENE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000411506500007 |
内容类型 | 期刊论文 |
源URL | [http://ir.nwipb.ac.cn/handle/363003/9806] ![]() |
专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
作者单位 | 1.Chinese Acad Sci, Northwest Inst Plateau Biol, Xining 810001, Qinghai, Peoples R China 2.Qufu Normal Univ, Key Lab Life Organ Anal, Qufu 273165, Shandong, Peoples R China 3.Qufu Normal Univ, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Xue, Fangfang,You, Jinmao,Qu, Fei,et al. Preparation of carbon nanodots capped by polyethylene glycol as a multifunctional sensor for temperature and paracetamol[J]. ANALYTICAL METHODS,2017,9(31):4533-4538. |
APA | Xue, Fangfang,You, Jinmao,Qu, Fei,&Liu, Jing.(2017).Preparation of carbon nanodots capped by polyethylene glycol as a multifunctional sensor for temperature and paracetamol.ANALYTICAL METHODS,9(31),4533-4538. |
MLA | Xue, Fangfang,et al."Preparation of carbon nanodots capped by polyethylene glycol as a multifunctional sensor for temperature and paracetamol".ANALYTICAL METHODS 9.31(2017):4533-4538. |
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