Near Infrared Quantum Cutting Luminescence of Er3+/Tm3+ Ion Pairs in a Telluride Glass | |
Liu, Jinying; Salamo, Gregory J.; Yang, Guojian; Lin, Wei; Tao, Jingfu; Yu, Chunlei; He, Lizhu; Zhao, Guoying; Wang, Kezhi; Hu, Lili | |
刊名 | Sci Rep
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2017 | |
卷号 | 7 |
通讯作者 | chen78xb@sina.com |
英文摘要 | The multiphoton near-infrared, quantum cutting luminescence in Er3+/Tm3+ co-doped telluride glass was studied. We found that the near-infrared 1800-nm luminescence intensity of (A) Er3+(8%) Tm3+(0.5%): telluride glass was approximately 4.4 to 19.5 times larger than that of (B) Tm3+(0.5%): telluride glass, and approximately 5.0 times larger than that of (C) Er3+(0.5%): telluride glass. Additionally, the infrared excitation spectra of the 1800 nm luminescence, as well as the visible excitation spectra of the 522 nm and 652 nm luminescence, of (A) Er3+(8%) Tm3+(0.5%): telluride glass are very similar to those of Er3+ ions in (C) Er3+(0.5%): telluride glass, with respect to the shapes of their excitation spectral waveforms and peak wavelengths. Moreover, we found that there is a strong spectral overlap and energy transfer between the infrared luminescence of Er3+ donor ions and the infrared absorption of Tm3+ acceptor ions. The efficiency of this energy transfer {I-4(13/2)(Er3+) -> I-4(15/2)(Er3+), H-3(6)(Tm3+) -> F-3(4)(Tm3+)} between the Er3+ and Tm3+ ions is approximately 69.8%. Therefore, we can conclude that the observed behaviour is an interesting multiphoton, near-infrared, quantum cutting luminescence phenomenon that occurs in novel Er3+-Tm3+ ion pairs. These findings are significant for the development of next-generation environmentally friendly germanium solar cells, and near-to-mid infrared (1.8-2.0 mu m) lasers pumped by GaN light emitting diodes. |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China [51472028]; Fundamental Research Funds for the Central Universities of China [2017TZ01] |
WOS记录号 | WOS:000401406700051 |
内容类型 | 期刊论文 |
源URL | [http://ir.siom.ac.cn/handle/181231/28305] ![]() |
专题 | 上海光学精密机械研究所_高功率激光单元技术研发中心 |
作者单位 | 中国科学院上海光学精密机械研究所 |
推荐引用方式 GB/T 7714 | Liu, Jinying,Salamo, Gregory J.,Yang, Guojian,et al. Near Infrared Quantum Cutting Luminescence of Er3+/Tm3+ Ion Pairs in a Telluride Glass[J]. Sci Rep,2017,7. |
APA | Liu, Jinying.,Salamo, Gregory J..,Yang, Guojian.,Lin, Wei.,Tao, Jingfu.,...&Chen, Xiaobo.(2017).Near Infrared Quantum Cutting Luminescence of Er3+/Tm3+ Ion Pairs in a Telluride Glass.Sci Rep,7. |
MLA | Liu, Jinying,et al."Near Infrared Quantum Cutting Luminescence of Er3+/Tm3+ Ion Pairs in a Telluride Glass".Sci Rep 7(2017). |
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