Direct Regioselective [3+2]-Cyclization Reactions of Ambivalent Electrophilic/Nucleophilic beta-Chlorovinyl Dithianes: Access to Cyclopentene Derivatives

doi:10.1021/acs.orglett.6b02536

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	Direct Regioselective [3+2]-Cyclization Reactions of Ambivalent Electrophilic/Nucleophilic beta-Chlorovinyl Dithianes: Access to Cyclopentene Derivatives
	Liang, YP; Lai, JS; Liu, T; Tang, SC; Tang, SC (reprint author), Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China.; Tang, SC (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
刊名	ORGANIC LETTERS
	2016-10-07
卷号	18 期号:1-19 页码:5086-5089
ISSN号	1523-7060
DOI	10.1021/acs.orglett.6b02536
文献子类	Article
英文摘要	The highly regioselective and operationally straightforward [3 + 2] cyclization of beta-chlorovinyl dithianes with alpha,beta-unsaturated carbonyl compounds have been developed. This protocol provides direct access to highly functionalized cyclopentenes with perfect chemo- and regioselectivities under extremely mild reaction conditions. In particular, the unprecedented cyclization allows for the selective preparation of hydroxylated cyclopentenes.
学科主题	Chemistry
出版地	WASHINGTON
资助项目	长江学者和创新团队发展计划 ; 中央高校基本科研业务费专项资金
项目编号	Qaohong Foundation ; PCSIRT [IRTI5R28] ; FRFCU [lzujbky-ct02]
语种	英语
WOS记录号	WOS:000385053900084
资助机构	MOE ; LZU
内容类型	期刊论文
源URL	[http://ir.lzu.edu.cn/handle/262010/189093]
专题	药学院_期刊论文
通讯作者	Tang, SC (reprint author), Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China.; Tang, SC (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
推荐引用方式 GB/T 7714	Liang, YP,Lai, JS,Liu, T,et al. Direct Regioselective [3+2]-Cyclization Reactions of Ambivalent Electrophilic/Nucleophilic beta-Chlorovinyl Dithianes: Access to Cyclopentene Derivatives[J]. ORGANIC LETTERS,2016,18(1-19):5086-5089.
APA	Liang, YP,Lai, JS,Liu, T,Tang, SC,Tang, SC ,&Tang, SC .(2016).Direct Regioselective [3+2]-Cyclization Reactions of Ambivalent Electrophilic/Nucleophilic beta-Chlorovinyl Dithianes: Access to Cyclopentene Derivatives.ORGANIC LETTERS,18(1-19),5086-5089.
MLA	Liang, YP,et al."Direct Regioselective [3+2]-Cyclization Reactions of Ambivalent Electrophilic/Nucleophilic beta-Chlorovinyl Dithianes: Access to Cyclopentene Derivatives".ORGANIC LETTERS 18.1-19(2016):5086-5089.