Di-tert-Butyl Peroxide-Mediated Atom-Transfer Radical Addition of 2-Chlorodithiane to Aryl Alkynes under Mild Conditions

doi:10.1002/chem.201502581

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	Di-tert-Butyl Peroxide-Mediated Atom-Transfer Radical Addition of 2-Chlorodithiane to Aryl Alkynes under Mild Conditions
	Lai, JS; Tian, LX; Liang, YP; Zhang, Y; Xie, XG; Fang, BW; Tang, SC; Tang, SC (reprint author), Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China.
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2015-10-05
卷号	21 期号:41 页码:14328-14331
关键词	alkynes atom transfer radical addition regioselectivity sulfur heterocycles
ISSN号	0947-6539
DOI	10.1002/chem.201502581
文献子类	Article
英文摘要	Atom transfer radical addition (ATRA) of 2-chlorodithiane onto aryl alkynes through the use of di-tert-butyl peroxide as an oxidant at room temperature directly affords a variety of synthetically valuable beta-chloro-(Z)-vinyl dithianes in good yields with high regioselectivities and without the assistance of any transition metals. It provides an operationally simple pathway to access vinyl dithianes with controlled formation of a new C(sp(2))-C bond and a C(sp(2))-Cl bond.
学科主题	Chemistry
出版地	WEINHEIM
资助项目	国家自然科学基金项目
项目编号	National Natural Science Foundation of China [21102064, 21102066, 21402153]
语种	英语
WOS记录号	WOS:000363331600013
资助机构	NSFC
内容类型	期刊论文
源URL	[http://ir.lzu.edu.cn/handle/262010/179561]
专题	药学院_期刊论文
通讯作者	Tang, SC (reprint author), Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China.
推荐引用方式 GB/T 7714	Lai, JS,Tian, LX,Liang, YP,et al. Di-tert-Butyl Peroxide-Mediated Atom-Transfer Radical Addition of 2-Chlorodithiane to Aryl Alkynes under Mild Conditions[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(41):14328-14331.
APA	Lai, JS.,Tian, LX.,Liang, YP.,Zhang, Y.,Xie, XG.,...&Tang, SC .(2015).Di-tert-Butyl Peroxide-Mediated Atom-Transfer Radical Addition of 2-Chlorodithiane to Aryl Alkynes under Mild Conditions.CHEMISTRY-A EUROPEAN JOURNAL,21(41),14328-14331.
MLA	Lai, JS,et al."Di-tert-Butyl Peroxide-Mediated Atom-Transfer Radical Addition of 2-Chlorodithiane to Aryl Alkynes under Mild Conditions".CHEMISTRY-A EUROPEAN JOURNAL 21.41(2015):14328-14331.