C-118 from fullerenols: Formation, structure and intermolecular nC(2) transfer reactions in mass spectrometry

	C-118 from fullerenols: Formation, structure and intermolecular nC(2) transfer reactions in mass spectrometry
	She YM ; Tu YP ; Liu SY
刊名	rapid communications in mass spectrometry
	1996
卷号	10 期号:6 页码:676-678
关键词	SOLID C-60 BUCKMINSTERFULLERENE CHEMISTRY CARBON
ISSN号	0951-4198
中文摘要	in fast atom bombardment, two fullerenols c-60(oh)(x) (x=13-15) and c-60(oh)(x) (x-24-26) gave rise to a group of ions centered at c-118 with intervals of 24 mass units in the high mass region. in contrast, no such ions appeared in the mass spectra of pure c-60, c-70 and other fullerene derivatives such as c-60(c6h5)(10), under the same conditions. it is proposed that the pinacol rearrangement of c-60(oh)(2), resulting from partial rupture of the polyhydroxy molecules, produces c-59 with two carbon atoms bearing an unpaired electron, and that dimerization of this reactive intermediate is responsible for the formation of the predominant product c-118. an intermolecular nc(2) transfer process is used to explain the symmetrical abundance distribution of these product ions in the spectra of fullerenols.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-22 ; 2011-06-09
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/25461]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	She YM,Tu YP,Liu SY. C-118 from fullerenols: Formation, structure and intermolecular nC(2) transfer reactions in mass spectrometry[J]. rapid communications in mass spectrometry,1996,10(6):676-678.
APA	She YM,Tu YP,&Liu SY.(1996).C-118 from fullerenols: Formation, structure and intermolecular nC(2) transfer reactions in mass spectrometry.rapid communications in mass spectrometry,10(6),676-678.
MLA	She YM,et al."C-118 from fullerenols: Formation, structure and intermolecular nC(2) transfer reactions in mass spectrometry".rapid communications in mass spectrometry 10.6(1996):676-678.