Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer

	Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer
	Sun XG ; Li B ; Lin YQ ; Jing XB
刊名	polymer international
	1996
卷号	41 期号:3 页码:301-305
关键词	LITHIUM PERCHLORATE POLY(PROPYLENE OXIDE) CONDUCTIVITY TEMPERATURE COMPLEXES LICLO4
ISSN号	0959-8103
通讯作者	sun xg
中文摘要	using a molal conductance method, ion solvation and ion association in polytriethylene glycol dimethacrylate (ptregd)-liclo4 gel electrolytes with amorphous ethylene oxide-co-propylene oxide (eo-co-po, <(m)over bar (n)>, = 1750) as the plasticizer were investigated. it was found that the fraction of solute existing as single ions (alpha(i)) and ion pairs (alpha(p)) decreases, while that of triple ions (alpha(t)) increases linearly with increasing salt concentration. the dependence of these fractions on molecular weight of plasticizer was also examined. it was shown that alpha(i) and alpha(t) increase and alpha(p) decreases with increasing molecular weight. the result of temperature dependence of these fractions was very interesting: when the temperature is lower than 55 degrees c, alpha(i) increases while alpha(p) and alpha(t) decrease with increasing temperature; however, when the temperature is higher than 55 degrees c, the reverse is true.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-22 ; 2011-06-09
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/25169]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Sun XG,Li B,Lin YQ,et al. Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer[J]. polymer international,1996,41(3):301-305.
APA	Sun XG,Li B,Lin YQ,&Jing XB.(1996).Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer.polymer international,41(3),301-305.
MLA	Sun XG,et al."Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer".polymer international 41.3(1996):301-305.