Electrochemical quartz crystal microbalance study for vanadium hexacyanoferrates: monitoring of film growth and ion effects during redox reactions

	Electrochemical quartz crystal microbalance study for vanadium hexacyanoferrates: monitoring of film growth and ion effects during redox reactions
	Wang Y ; Zhu GY ; Wang EK
刊名	journal of electroanalytical chemistry
	1997
卷号	430 期号:1-2 页码:127-132
关键词	PRUSSIAN-BLUE FILMS THIN-FILMS CHARGE-TRANSFER ELECTRODES CONDUCTIVITY MECHANISMS DEPOSITION TRANSPORT SURFACES SORPTION
ISSN号	0022-0728
通讯作者	zhu gy
中文摘要	an electrochemical quartz crystal microbalance was employed to monitor directly the growth of vanadium hexacyanoferrate (vhf) films on platinum substrates during electrodeposition and interfacial coagulation in the solution containing sulfuric acid electrolyte, vanadium(iv) and hexacyanoferrate(iii). mass changes of the gold/crystal working electrode were correlated with cyclic voltammetry data. effects of cations (nh4+, li+, na+ and k+), anions (so42- and no3-) and solvent during redox reactions of the films were studied. the results show that cations were incorporated into the film during reduction and expelled from the film during oxidation. solvent also participates in vhf electrochemistry, and its role cannot be neglected. anions play no role in vhf electrochemistry. (c) 1997 elsevier science s.a.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000071052300013
公开日期	2010-12-22
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/23887]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wang Y,Zhu GY,Wang EK. Electrochemical quartz crystal microbalance study for vanadium hexacyanoferrates: monitoring of film growth and ion effects during redox reactions[J]. journal of electroanalytical chemistry,1997,430(1-2):127-132.
APA	Wang Y,Zhu GY,&Wang EK.(1997).Electrochemical quartz crystal microbalance study for vanadium hexacyanoferrates: monitoring of film growth and ion effects during redox reactions.journal of electroanalytical chemistry,430(1-2),127-132.
MLA	Wang Y,et al."Electrochemical quartz crystal microbalance study for vanadium hexacyanoferrates: monitoring of film growth and ion effects during redox reactions".journal of electroanalytical chemistry 430.1-2(1997):127-132.