An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II)

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II)
	Xiao, LL (Xiao, Lili); Wang, BW (Wang, Biwei); Ji, L (Ji, Li); Wang, F (Wang, Fu); Yuan, QH (Yuan, Qunhui); Hu, GZ (Hu, Guangzhi); Dong, AG (Dong, Angang); Gan, W (Gan, Wei)
刊名	ELECTROCHIMICA ACTA
	2016
卷号	222 期号:12 页码:1371-1377
关键词	Three-dimensionally interconnected mesoporous graphene framework Bismuth film Differential pulse anodic stripping voltammetry Cd( II) Pb( II)
通讯作者	Yuan, QH
英文摘要	Recently, ordered mesoporous carbon has displayed attractive performance in electrochemical catalysis and sensing, benefiting from its rich and tunable pore texture. In this work, a novel electrochemical sensor based on a three-dimensionally interconnected mesoporous graphene framework (MGF) was developed for simultaneous determination of Cd(II) and Pb(II) in aqueous solution. Attributable to the abundant three-dimensional mesopores and good electrical conductivity of MGF, as well as the synergistic effect of Nafion and in-situ plated bismuth films, a highly sensitive determination of mixed metals at a Bi/MGF-Nafion/ GCE is achieved. The proposed sensor exhibits wide linear responses for Cd(II) and Pb(II), ranging from 2-70 mu g L (1) and 0.5-110 mu g L (1), respectively. The detection limits are about 0.5 and 0.1 mu g L (1) for Cd(II) and Pb(II), respectively, which are about 6 and 100 times lower than the drinking water standards set by the World Health Organization (WHO). Moreover, Bi/MGF-Nafion/ GCE has been applied for the detection of mixed metals in real water samples. The satisfying recoveries (87.5-109.2%) and relative standard deviations (RSD, 3.7-8.6%) make the proposed electrode a promising candidate for rapid and on-site monitoring of environmental metallic pollutants.
收录类别	SCI
WOS记录号	WOS:000395443700046
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4881]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Key Lab Funct Mat & Dev Special Environm, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Fudan Univ, Collaborat Innovat Ctr Chem Energy Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China 4.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China 5.Harbin Inst Technol, Sch Mat Sci & Engn, Shenzhen 518055, Peoples R China 6.Harbin Inst Technol, Sch Nat Sci & Humanities, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Xiao, LL ,Wang, BW ,Ji, L ,et al. An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II)[J]. ELECTROCHIMICA ACTA,2016,222(12):1371-1377.
APA	Xiao, LL .,Wang, BW .,Ji, L .,Wang, F .,Yuan, QH .,...&Gan, W .(2016).An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II).ELECTROCHIMICA ACTA,222(12),1371-1377.
MLA	Xiao, LL ,et al."An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II)".ELECTROCHIMICA ACTA 222.12(2016):1371-1377.