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The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments
Qian, Hongchang ; Zhang, Dawei ; Deng, Leping ; Huang, Luyao ; Xu, Dake ; Du, Cuiwei ; Li, Xiaogang
刊名PROGRESS IN ORGANIC COATINGS
2017-03-01
卷号104页码:199-209
关键词Organic coatings Corrosion EIS Hydrophobicity Interfaces
ISSN号0300-9440
通讯作者Zhang, DW ; Xu, DK (reprint author), Univ Sci & Technol Beijing, Ctr Corros & Protect, Beijing 100083, Peoples R China.
中文摘要Hydrophobic epoxy coatings with particulated surfaces were prepared via soft lithography using different abrasive papers as the templates. With the increasing surface roughness, the hydrophobicity of these surfaces first increased and then decreased and a maximum water contact angle of similar to 136 degrees was obtained by using a P2000 abrasive paper as the template. Electrochemical impedance spectroscopy (EIS) was used to study the role of surface morphology in the coatings' barrier properties under wet-dry cyclic immersion and in salt-spray environments. The results demonstrated that the hydrophobicity induced by the trapped air in the surface microstructures produced stronger-barrier properties than that produced by a smooth coating when exposed to wet-dry cyclic immersion. The strongest barrier performance was achieved by the coating templated with the P2000 abrasive paper, However, these microstructured hydrophobic coatings deteriorated faster in the salt-spray tests because of the direct deposition of salt electrolyte particles on the coating surfaces and the increased coating surface area. Under the salt spray condition, the coating obtained from P6000 abrasive paper exhibited the fastest deterioration. (C) 2016 Elsevier B.V. All rights reserved.
学科主题Chemistry, Applied ; Materials Science, Coatings & Films
收录类别SCI
资助信息National Natural Science Foundation of China [51401018]; Fundamental Research Funds for the Central Universities [FRF-TP-15-054A2]; National Basic Research Program of China (973 Program) [2014CB643300]; Open Fund of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences [MCKF201609]
语种英语
公开日期2017-08-17
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/78266]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
Qian, Hongchang,Zhang, Dawei,Deng, Leping,et al. The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments[J]. PROGRESS IN ORGANIC COATINGS,2017,104:199-209.
APA Qian, Hongchang.,Zhang, Dawei.,Deng, Leping.,Huang, Luyao.,Xu, Dake.,...&Li, Xiaogang.(2017).The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments.PROGRESS IN ORGANIC COATINGS,104,199-209.
MLA Qian, Hongchang,et al."The role of surface morphology in the barrier properties of epoxy coatings in different corrosion environments".PROGRESS IN ORGANIC COATINGS 104(2017):199-209.
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