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Electrochemical Behavior of Three 90Cu-10Ni Tubes from Different Manufacturers After Immersion in 3.5% NaCl Solution
Ekerenam, Okpo O. ; Ma, Aili ; Zheng, Yugui ; Emori, Wilfred
刊名JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
2017-04-01
卷号26期号:4页码:1701-1716
关键词corrosion and wear corrosion product film EIS nonferrous metals oxidation polarization curves XPS
ISSN号1059-9495
通讯作者Ma, AL (reprint author), Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, 62 Wencui Rd, Shenyang 110016, Peoples R China.
中文摘要Investigation on the electrochemical behavior and corrosion product films formed on three 90Cu-10Ni tubes designated as Tubes A, B and C from three different manufacturers with different service lives were carried out using electrochemical techniques, SEM, XRD and XPS after immersion in 3.5 wt.% NaCl solution. The results of polarization curve measurements showed noticeable decrease in the corrosion current densities (I (corr)) of the three tubes with immersion time, and the I (corr) of Tube C was comparatively lower than those of Tubes A and B at early immersion period. EIS measurements revealed duplex film layers on the surface of the samples with the inner film formation occurring at different times for different tubes as the film resistance R (f2) revealed the formation of the inner compact layer in Tube C after 15-day immersion and in Tubes A and B after 30 days. Tube C showed better corrosion resistance which is due to early formation of the inner compact oxide film. The XPS analysis revealed Ni enrichment on the surface film of the three samples but Ni depletion as the immersion time is increased.
学科主题Materials Science, Multidisciplinary
收录类别SCI
资助信息National Natural Science Foundation of China [Y7F2131111]; National Environmental Corrosion Platform [2005DKA10400]
语种英语
公开日期2017-08-17
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/78205]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
Ekerenam, Okpo O.,Ma, Aili,Zheng, Yugui,et al. Electrochemical Behavior of Three 90Cu-10Ni Tubes from Different Manufacturers After Immersion in 3.5% NaCl Solution[J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,2017,26(4):1701-1716.
APA Ekerenam, Okpo O.,Ma, Aili,Zheng, Yugui,&Emori, Wilfred.(2017).Electrochemical Behavior of Three 90Cu-10Ni Tubes from Different Manufacturers After Immersion in 3.5% NaCl Solution.JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,26(4),1701-1716.
MLA Ekerenam, Okpo O.,et al."Electrochemical Behavior of Three 90Cu-10Ni Tubes from Different Manufacturers After Immersion in 3.5% NaCl Solution".JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE 26.4(2017):1701-1716.
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