A Mononuclear Nonheme Iron(V)-Imido Complex

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	A Mononuclear Nonheme Iron(V)-Imido Complex
	Seungwoo Hong 1,2; Kyle D. Sutherlin 3; Anil Kumar Vardhaman 1; James J. Yan 3; Sora Park 1; Lee, Yong-Min 1; Soojeong Jang 1; Lu, Xiaoyan 1; Takehiro Ohta 4; Takashi Ogura 4
刊名	Journal of the American Chemical Society
	2017
卷号	139 期号:26 页码:8800-8803
ISSN号	0002-7863
通讯作者	Edward I. Solomon ; Wonwoo Nam
英文摘要	Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe^V(NTs)]⁻ (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe—N bond length of 1.65(4) Å, and an Fe—N vibration at 817 cm^–1. The reactivity of 1 was demonstrated in C—H bond functionalization and nitrene transfer reactions.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	NRF of Korea through CRI (NRF-2012R1A3A2048842 to W.N.);GRL (NRF-2010-00353 to W.N.);MSIP (NRF-2017R1C1B2002037 to S.H.);Sookmyung Women’s University Grants (1-1603-2054 to S.H.);Funding for this work was also provided by the NIH (GM-40392 to E.I.S.);T.O. acknowledges the support of “Strategic Young Researcher Overseas Visits Program for Accelerating Brain Circulation” and Grant-in-Aid for Scientific Research (No. 15H00960) by JSPS;Use of the SSRL, SLAC National Accelerator Laboratory, is supported by the U.S. DOE under Contract No. DE-AC02-76SF00515
语种	英语
WOS记录号	WOS:000405158900006
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/22108]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea 2.Sookmyung Womens Univ, Dept Chem, Seoul 04310, South Korea 3.Stanford Univ, Dept Chem, Stanford, CA 94305 USA 4.Univ Hyogo, Grad Sch Life Sci, Picobiol Inst, RSC UH LP Ctr, Kobe, Hyogo 6795148, Japan 5.Stanford Linear Accelerator Ctr, Stanford Synchrotron Radiat Lab, Menlo Pk, CA 94025 USA 6.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Seungwoo Hong,Kyle D. Sutherlin,Anil Kumar Vardhaman,et al. A Mononuclear Nonheme Iron(V)-Imido Complex[J]. Journal of the American Chemical Society,2017,139(26):8800-8803.
APA	Seungwoo Hong.,Kyle D. Sutherlin.,Anil Kumar Vardhaman.,James J. Yan.,Sora Park.,...&Wonwoo Nam.(2017).A Mononuclear Nonheme Iron(V)-Imido Complex.Journal of the American Chemical Society,139(26),8800-8803.
MLA	Seungwoo Hong,et al."A Mononuclear Nonheme Iron(V)-Imido Complex".Journal of the American Chemical Society 139.26(2017):8800-8803.