Synthesis of benzimidazoles from o-phenylenediamines and DMF derivatives in the presence of PhSiH3
Zhu, Jianhua1; Zhang ZB(张震北)2,3; Miao CX(苗成霞)2; Liu, Wei1; Sun W(孙伟)2
刊名Tetrahedron
2017
卷号73期号:25页码:3458-3462
关键词Benzimidazoles PhSiH3 o-Phenylenediamines N,N-Dimethylformamide Cyclization reaction
ISSN号0040-4020
通讯作者孙伟 ; Liu, Wei
英文摘要

A simple approach to preparation of benzimidazoles from o-phenylenediamines and DMF derivatives, only employing PhSiH3 as promoter without any other additives, was reported. This route provided moderate to high yields with a broad substrate scope. A plausible mechanism for the reaction is proposed based on the spectroscopic characterization (e.g., HRMS and 1H NMR) of the reaction mixture.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (21402101 to W.L.;21473226 to W.S.)
语种英语
WOS记录号WOS:000403526600008
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/22051]  
专题兰州化学物理研究所_苏州研究院
兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Nantong Univ, Dept Pharm, Nantong 226000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Jianhua,Zhang ZB,Miao CX,et al. Synthesis of benzimidazoles from o-phenylenediamines and DMF derivatives in the presence of PhSiH3[J]. Tetrahedron,2017,73(25):3458-3462.
APA Zhu, Jianhua,Zhang ZB,Miao CX,Liu, Wei,&Sun W.(2017).Synthesis of benzimidazoles from o-phenylenediamines and DMF derivatives in the presence of PhSiH3.Tetrahedron,73(25),3458-3462.
MLA Zhu, Jianhua,et al."Synthesis of benzimidazoles from o-phenylenediamines and DMF derivatives in the presence of PhSiH3".Tetrahedron 73.25(2017):3458-3462.
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