Effect of the desilication of H-ZSM-5 by alkali treatment on the catalytic performance in Fischer-Tropsch synthesis | |
Wang, Yuelun1; Li, Xinlong1; Ma, Hao1; Zhang, Hong1; Jiang, Yuan1; Wang, Hui2; Li, Zhuo2; Wu, Jinhu2 | |
刊名 | REACTION KINETICS MECHANISMS AND CATALYSIS |
2017-04-01 | |
卷号 | 120期号:2页码:775-790 |
关键词 | Fischer-Tropsch synthesis Cobalt catalyst Alkali treatment Hierarchical zeolites |
英文摘要 | Hierarchical HZSM-5 zeolites were prepared by post-synthesis treatment of HZSM-5 zeolite with different concentrations of NaOH. The physicochemical properties of these zeolites loaded by cobalt nanoparticles in Fischer-Tropsch (FT) synthesis were investigated. It was found that the activity and CH4 selectivity increased at first, then decreased closely related to the change of catalyst reducibility indicating that higher cobalt reducibility was a prerequisite for hierarchical zeolites to improve FT catalytic performances. The catalyst treated with 0.1 M NaOH was found to be optimal for C12-18 selectivity, which was mainly attributed to bimodal porous structure to improve diffusion behavior of products combining with moderate acid sites to mitigate second reactions. While the catalyst treated with 0.15 M NaOH showed the lowest activity and higher CH4 selectivity due to its lower reducibility even the largest mesopores were observed. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | SUPPORTED RUTHENIUM NANOPARTICLES ; COBALT CATALYSTS ; ZEOLITE ZSM-5 ; MFI ZEOLITES ; C-5-C-11 ISOPARAFFINS ; MASS-TRANSFER ; PORE-SIZE ; SYNGAS ; SILICA ; SELECTIVITY |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000398722100025 |
内容类型 | 期刊论文 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/9288] |
专题 | 青岛生物能源与过程研究所_热化学转化事业部 |
作者单位 | 1.China Univ Min & Technol, Key Lab Coal Proc & Efficient Utilizat, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuel, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Yuelun,Li, Xinlong,Ma, Hao,et al. Effect of the desilication of H-ZSM-5 by alkali treatment on the catalytic performance in Fischer-Tropsch synthesis[J]. REACTION KINETICS MECHANISMS AND CATALYSIS,2017,120(2):775-790. |
APA | Wang, Yuelun.,Li, Xinlong.,Ma, Hao.,Zhang, Hong.,Jiang, Yuan.,...&Wu, Jinhu.(2017).Effect of the desilication of H-ZSM-5 by alkali treatment on the catalytic performance in Fischer-Tropsch synthesis.REACTION KINETICS MECHANISMS AND CATALYSIS,120(2),775-790. |
MLA | Wang, Yuelun,et al."Effect of the desilication of H-ZSM-5 by alkali treatment on the catalytic performance in Fischer-Tropsch synthesis".REACTION KINETICS MECHANISMS AND CATALYSIS 120.2(2017):775-790. |
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