Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel-Fuel Components

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 绿色化学催化团队

	Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel-Fuel Components
	Liu, Qiang 1,2; Xu, Guoqiang 1; Wang, Xicheng 1; Liu, Xiaoran 1,2; Mu, Xindong 1
刊名	CHEMSUSCHEM
	2016-12-20
卷号	9 期号:24 页码:3465-3472
关键词	alcohols condensation long-chain oxygenates palladium supported catalysts
英文摘要	In light of the increasing concern about the energy and environmental problems caused by the combustion of petroleum-based fuels (e.g., jet and diesel fuels), the development of new procedures for their sustainable production from renewable biomass-derived platform compounds has attracted tremendous attention recently. Long-chain ketones/alcohols are promising fuel components owing to the fuel properties that closely resemble those of traditional fuels. The focus of this report is the production of long-chain ketones/alcohols by direct upgrading of biomass-derived short-chain alcohol mixtures (e.g., isopropanol-butanol-ethanol mixtures) in pure water. An efficient Pd catalyst system was developed for these highly selective transformations. Long-chain ketones/alcohols (C-8-C-19), which can be used as precursors for renewable jet/diesel fuel, were obtained in good-to-high selectivity (>90%) by using the developed Pd catalyst.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	N-DOPED CARBON ; ENGINEERING CLOSTRIDIUM-ACETOBUTYLICUM ; CATALYTIC CONVERSION ; TRANSPORTATION FUELS ; BORROWING HYDROGEN ; PALLADIUM CATALYST ; PLATFORM MOLECULES ; ESCHERICHIA-COLI ; ALPHA-ALKYLATION ; PD NANOPARTICLES
收录类别	SCI
语种	英语
WOS记录号	WOS:000394571500015
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/9320]
专题	青岛生物能源与过程研究所_绿色化学催化团队
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Qiang,Xu, Guoqiang,Wang, Xicheng,et al. Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel-Fuel Components[J]. CHEMSUSCHEM,2016,9(24):3465-3472.
APA	Liu, Qiang,Xu, Guoqiang,Wang, Xicheng,Liu, Xiaoran,&Mu, Xindong.(2016).Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel-Fuel Components.CHEMSUSCHEM,9(24),3465-3472.
MLA	Liu, Qiang,et al."Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel-Fuel Components".CHEMSUSCHEM 9.24(2016):3465-3472.