Dispersive liquid-liquid microextraction for four phenolic environmental estrogens in water samples followed by determination using capillary electrophoresis

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 中科院海岸带环境过程与生态修复重点实验室

	Dispersive liquid-liquid microextraction for four phenolic environmental estrogens in water samples followed by determination using capillary electrophoresis
	Liu, Junying ; Lu, Wenhui ; Liu, Huitao ; Wu, Xiaqing ; Li, Jinhua; Chen, Lingxin
刊名	ELECTROPHORESIS
	2016-10
卷号	37 期号:19 SI 页码:2502-2508
关键词	MICELLAR ELECTROKINETIC CHROMATOGRAPHY SOLID-PHASE EXTRACTION TANDEM MASS-SPECTROMETRY CLOUD-POINT EXTRACTION URINARY PORPHYRINS ORGANIC-COMPOUNDS MILK SAMPLES BISPHENOL-A DIETHYLSTILBESTROL SEPARATION
ISSN号	0173-0835
通讯作者	Liu, HT
产权排序	[Liu, Junying; Liu, Huitao; Chen, Lingxin] Yantai Univ, Coll Chem & Chem Engn, Yantai, Peoples R China; [Liu, Junying; Lu, Wenhui; Wu, Xiaqing; Li, Jinhua; Chen, Lingxin] Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res, Yantai, Peoples R China
英文摘要	Dispersive liquid-liquid microextraction (DLLME) coupled with CE was successfully developed for simultaneous determination of four types of phenolic environmental estrogens (PEEs), namely hexestrol (HS), bisphenol A (BPA), diethylstilbestrol (DES) and dienestrol (DS). Several parameters affecting DLLME and CE conditions were systematically investigated including the type and volume of extraction solvent and dispersive solvent, extraction time, salt, pH value, surfactant, buffer solution and so on. Under the optimal conditions, DLLME-CE exhibited strong enrichment ability, presenting high enrichment factors of 467, 241, 367 and 362 for HS, BPA, DES and DS, respectively, as well as low detection limits of 0.3, 0.6, 0.6 and 0.3 mu g/L, respectively. Excellent linearity was achieved in the range of 2.0-150 mu g/L for HS andDS, and 4.0-300 mu g/L for BPA and DES, with correlation coefficients R>0.9983. Recoveries ranging from 70.4 to 108.1% were obtained with tap water, lake water and seawater samples spiked at three concentration levels and the relative standard deviations (RSDs, for n = 5) were 2.1-9.7%. This DLLME-CE method with high selectivity and sensitivity, high stability, simplicity, cost-effectiveness, eco-friendliness was proved potentially applicable for the rapid and simultaneous determination of PEEs in complicated water samples.
学科主题	Biochemistry & Molecular Biology ; Chemistry
研究领域[WOS]	Biochemistry & Molecular Biology; Chemistry
关键词[WOS]	MICELLAR ELECTROKINETIC CHROMATOGRAPHY ; SOLID-PHASE EXTRACTION ; TANDEM MASS-SPECTROMETRY ; CLOUD-POINT EXTRACTION ; URINARY PORPHYRINS ; ORGANIC-COMPOUNDS ; MILK SAMPLES ; BISPHENOL-A ; DIETHYLSTILBESTROL ; SEPARATION
收录类别	SCI
原文出处	10.1002/elps.201500519
语种	英语
WOS记录号	WOS:000388595400009
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/22077]
专题	烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位	1.Yantai Univ, Coll Chem & Chem Engn, Yantai, Peoples R China 2.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res, Yantai, Peoples R China 3.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res, Yantai, Peoples R China
推荐引用方式 GB/T 7714	Liu, Junying,Lu, Wenhui,Liu, Huitao,et al. Dispersive liquid-liquid microextraction for four phenolic environmental estrogens in water samples followed by determination using capillary electrophoresis[J]. ELECTROPHORESIS,2016,37(19 SI):2502-2508.
APA	Liu, Junying,Lu, Wenhui,Liu, Huitao,Wu, Xiaqing,Li, Jinhua,&Chen, Lingxin.(2016).Dispersive liquid-liquid microextraction for four phenolic environmental estrogens in water samples followed by determination using capillary electrophoresis.ELECTROPHORESIS,37(19 SI),2502-2508.
MLA	Liu, Junying,et al."Dispersive liquid-liquid microextraction for four phenolic environmental estrogens in water samples followed by determination using capillary electrophoresis".ELECTROPHORESIS 37.19 SI(2016):2502-2508.